Mg alloy for hydrogen storage processed by SPD

被引:53
作者
Leiva, Daniel R. [2 ,3 ]
Fruchart, Daniel [2 ,3 ]
Bacia, Maria [2 ,3 ]
Girard, Gregory [2 ,3 ]
Skryabina, Natalya [4 ]
Villela, Andre C. S. [2 ,3 ]
Miraglia, Salvatore [2 ,3 ]
Santos, Dilson S. [5 ]
Botta, Walter J. [1 ]
机构
[1] Univ Fed Sao Carlos, LabNano, Dept Mat Engn, BR-13565905 Sao Carlos, SP, Brazil
[2] Univ Grenoble 1, Grenoble, France
[3] CNRS, Inst Neel, Grenoble, France
[4] Perm State Univ, Dept Phys, Perm, Russia
[5] Univ Fed Rio de Janeiro, COPPE, BR-21945 Rio De Janeiro, Brazil
关键词
Mg alloys; Hydrogen storage; SPD; Nanostructures; LOW-TEMPERATURE SUPERPLASTICITY; MAGNESIUM ALLOY; H-SORPTION; GRAINED MATERIALS; ZK60; ALLOY; NANOPARTICLES; DUCTILITY; KINETICS; TEXTURE; POWDERS;
D O I
10.3139/146.110225
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Mg-based nanocomposites are promising candidates for hydrogen storage applications exhibiting fast H-sorption kinetics at reasonably low temperatures when processed by high-energy ball milling techniques. However, since compaction of the highly reactive nanometric powder is desirable before application, the search for other effective processing routes for the preparation of Mg-based nanocomposites is relevant. In this work, we have used a combination of equal channel angular pressing, cold rolling and high-energy ball milling in the processing of the commercial AZ31 extruded alloy to evaluate its use as a hydrogen storage material. Severe plastic deformation carried out at different temperatures. combined with further mechanical processing resulted in a controlled texture and signifiant grain refinement, which are desirable microstructural characteristics for hydrogen storage applications.
引用
收藏
页码:1739 / 1746
页数:8
相关论文
共 26 条
  • [1] Improving H-sorption in MgH2 powders by addition of nanoparticles of transition metal fluoride catalysts and mechanical alloying
    de Castro, JFR
    Yavari, AR
    LeMoulec, A
    Ishikawa, TT
    Botta, WJ
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 389 (1-2) : 270 - 274
  • [2] de Rango P., 2007, J ALLOY COMPD, V52, P446
  • [3] H-sorption in MgH2 nanocomposites containing Fe or Ni with fluorine
    Deledda, S
    Borissova, A
    Poinsignon, C
    Botta, WJ
    Dornheim, M
    Klassen, T
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 404 : 409 - 412
  • [4] DUFOUR J, 2007, J ALLOYS COMPD L, V5, P439
  • [5] DUFOUR J, 2007, J ALLOY COMPD, V147, P446
  • [6] Record superplastic ductility in a magnesium alloy processed by equal-channel angular pressing
    Figueiredo, Roberto B.
    Langdon, Terence G.
    [J]. ADVANCED ENGINEERING MATERIALS, 2008, 10 (1-2) : 37 - 40
  • [7] The development of superplastic ductilities and microstructural homogeneity in a magnesium ZK60 alloy processed by ECAP
    Figueiredo, Roberto B.
    Langdon, Terence G.
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 430 (1-2): : 151 - 156
  • [8] The shearing characteristics associated with equal-channel angular pressing
    Furukawa, M
    Iwahashi, Y
    Horita, Z
    Nemoto, M
    Langdon, TG
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1998, 257 (02): : 328 - 332
  • [9] Principle of equal-channel angular pressing for the processing of ultra-fine grained materials
    Iwahashi, Y
    Wang, JT
    Horita, Z
    Nemoto, M
    Langdon, TG
    [J]. SCRIPTA MATERIALIA, 1996, 35 (02) : 143 - 146
  • [10] Deformation and fracture during equal channel angular pressing of AZ31 magnesium alloy
    Kang, Feng
    Wang, Jing Tao
    Peng, Yong
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2008, 487 (1-2): : 68 - 73