Facile preparation of PbO2 electrode for the electrochemical inactivation of microorganisms

被引:17
作者
Chen, Quanpeng [2 ]
Ai, Shiyun [1 ]
Li, Shasha [3 ]
Xu, Jing [1 ]
Yin, Huanshun [1 ]
Ma, Qiang [1 ]
机构
[1] Shandong Agr Univ, Coll Chem & Mat Sci, Tai An 271018, Shandong, Peoples R China
[2] Shandong Agr Univ, Coll Resources & Environm, Tai An 271018, Shandong, Peoples R China
[3] Shandong Agr Univ, Coll Anim Sci & Technol, Tai An 271018, Shandong, Peoples R China
关键词
PbO2; electrode; Ionic liquids; Electrodeposition; Electrochemical disinfection; Escherichia coli; DRINKING-WATER; ELECTROCATALYSIS; DISINFECTION; DEGRADATION; OXIDATION; PHENOL;
D O I
10.1016/j.elecom.2009.09.038
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The electrochemical inactivation of microorganisms using Escherichia coli as testing species by a novel PbO2 electrode was investigated. The PbO2 electrode was constructed by electrochemical deposition of PbO2 on the treated Ti substrate in the fluorine (F) doped ionic liquids/water (ILs/H2O) two phase solution. Then, it was characterized by XRD and SEM analysis. Further investigation showed that the crystal size of electrodeposited PbO2 became smaller with the increase of ILs concentration in the electrolyte solution. The small crystal size favored to the generation of the absorbable (OH)-O-center dot on the electrode surface, which was proved to play a key role during the disinfection process. TEM investigation revealed the morphological change of the E call cells during the bactericidal process. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:2233 / 2236
页数:4
相关论文
共 17 条
[1]   Study on production of free hydroxyl radical and its reaction with salicylic acid at lead dioxide electrode [J].
Ai, SY ;
Wang, QJ ;
Li, H ;
Jin, LT .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2005, 578 (02) :223-229
[2]   Ionic liquids for the convenient synthesis of functional nanoparticles and other inorganic nanostructures [J].
Antonietti, M ;
Kuang, DB ;
Smarsly, B ;
Yong, Z .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (38) :4988-4992
[3]   Electrocatalytic degradation of 4-chlorophenol on F-doped PbO2 anodes [J].
Cao, Jianglin ;
Zhao, Haiyan ;
Cao, Fahe ;
Zhang, Jianqing ;
Cao, Chunan .
ELECTROCHIMICA ACTA, 2009, 54 (09) :2595-2602
[4]  
Gaskova D, 1996, BIOELECTROCH BIOENER, V39, P195
[5]   Electrodeposition of zinc-magnesium alloy from 1-ethyl-3-methylimidazorium bromide molten salt [J].
Iwagishi, T ;
Sawada, K ;
Yamamoto, H ;
Koyama, K ;
Shirai, H .
ELECTROCHEMISTRY, 2003, 71 (05) :318-321
[6]   The role of reactive oxygen species in the electrochemical inactivation of microorganisms [J].
Jeong, Joonseon ;
Kim, Jee Yeon ;
Yoon, Jeyong .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2006, 40 (19) :6117-6122
[7]   ELECTROCATALYSIS OF ANODIC OXYGEN-TRANSFER REACTIONS - OXIDATION OF PHENOL AND BENZENE AT BISMUTH-DOPED LEAD DIOXIDE ELECTRODES IN ACIDIC SOLUTIONS [J].
KAWAGOE, KT ;
JOHNSON, DC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (12) :3404-3409
[8]   Inactivation of Microcystis aeruginosa by continuous electrochemical cycling process in tube using Ti/RuO2 electrodes [J].
Liang, WY ;
Qu, JH ;
Chen, LB ;
Liu, HJ ;
Lei, PJ .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (12) :4633-4639
[9]  
LIU WK, 1997, J ANTIMICROB CHEMOTH, V61, P163
[10]   DISINFECTION OF DRINKING-WATER BY USING A NOVEL ELECTROCHEMICAL REACTOR EMPLOYING CARBON-CLOTH ELECTRODES [J].
MATSUNAGA, T ;
NAKASONO, S ;
TAKAMUKU, T ;
BURGESS, JG ;
NAKAMURA, N ;
SODE, K .
APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 1992, 58 (02) :686-689