The solubility of CO(2) in aqueous blends of diethanolamine (DEA) and piperazine (PZ), from mixtures of CO(2) and N(2), was measured for temperatures and CO(2) partial pressures ranging from (303.14 to 353.14) K and (10.133 to 20.265) kPa, respectively. Measurements were made by a saturation method using a laboratory scale bubble column. The results of CO(2) solubility in liquid are expressed as alpha(CO2) (mol CO(2)/mol amine) for all experimental runs. A solubility model is developed to correlate and predict the solubility data Of CO(2) in aqueous blends of DEA and PZ. There is all acceptable degree of agreement between the experimental data of the present Study and predictions of the solubility model with an average absolute deviation of less than 4.5 %.
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Univ Malaya, Dept Chem Engn, Kuala Lumpur 50603, Malaysia
Univ Al Mustansiriyah, Dept Mat Engn, Baghdad 10052, IraqUniv Malaya, Dept Chem Engn, Kuala Lumpur 50603, Malaysia
Ghalib, Lubna
Ali, Brahim Si
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Univ Malaya, Dept Chem Engn, Kuala Lumpur 50603, MalaysiaUniv Malaya, Dept Chem Engn, Kuala Lumpur 50603, Malaysia