Synthesis of Reduced Graphene Oxide as a Support for Nano Copper and Palladium/Copper Catalysts for Selective NO Reduction by CO

被引：49

作者：

do Nascimento, Jessica Rabelo ^{[1
]}

D'Oliveira, Monique Ribeiro ^{[1
]}

Veiga, Amanda Garcez ^{[2
]}

Chagas, Carlos Alberto ^{[3
]}

Schmal, Martin ^{[1
,4
]}

机构：

[1] Univ Fed Rio de Janeiro, COPPE PENt, Nanotechnol Engn Program, BR-21941972 Rio De Janeiro, RJ, Brazil

[2] Univ Fed Rio de Janeiro, Inst Chem, BR-21941909 Rio De Janeiro, RJ, Brazil

[3] Univ Fed Rio de Janeiro, Sch Chem, BR-21941909 Rio De Janeiro, RJ, Brazil

[4] Univ Fed Rio de Janeiro, COPPE PEQ NUCAT, Chem Engn Program, BR-21941972 Rio De Janeiro, RJ, Brazil

来源：

ACS OMEGA | 2020年 / 5卷 / 40期

关键词：

NANOPARTICLES; CU; SPECTROSCOPY; ADSORPTION; SURFACE; NI;

D O I：

10.1021/acsomega.0c02417

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper and palladium/copper nanoparticles supported on reduced graphene oxide catalysts were synthesized and evaluated for the selective NO reduction by CO. The catalysts were characterized by XRD, nitrogen adsorption-desorption, TGA, XPS, TPR, in situ XRD, STEM, and HRTEM. The STEM and HRTEM results showed high metal oxide dispersions on the rGO. XPS results showed the presence of Cu and Pd oxide species. The reduction of copper supported on the rGO occurred in two steps for CuOx/rGO(c), while that for CuOx-PdOy/rGO(c) occurred in one step for temperatures lower than 350 degrees C. Noteworthy is that the in situ XRD results showed that the rGO structure was not affected after reduction at 350 degrees C. The in situ XRD of reduction revealed the appearance of new phases for copper during the reduction. The catalysts were evaluated in NO reduction by CO. The tests showed that the reduced catalysts presented high performance with NO conversions and N-2 selectivity above 85% at 350 degrees C.

引用

页码：25568 / 25581

页数：14

共 62 条

[41] Activity enhancement of mixed lanthanum-copper-iron-perovskites in the CO plus NO reaction [J].

Peter, SD ;

Garbowski, E ;

Perrichon, V ;

Pommier, B ;

Primet, M .

APPLIED CATALYSIS A-GENERAL, 2001, 205 (1-2) :147-158

[42] The role of surface oxygenated-species and adsorbed hydrogen in the oxygen reduction reaction (ORR) mechanism and product selectivity on Pd-based catalysts in acid media [J].

Rahul, R. ;

Singh, R. K. ;

Bera, B. ;

Devivaraprasad, R. ;

Neergat, M. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (23) :15146-15155

[43] A facile synthesis of Cu-Ni bimetallic nanoparticle supported organo functionalized graphene oxide as a catalyst for selective hydrogenation of p-nitrophenol and cinnamaldehyde [J].

Rana, Surjyakanta ;

Jonnalagadda, Sreekantha B. .

RSC ADVANCES, 2017, 7 (05) :2869-2879

[44] Organo functionalized graphene with Pd nanoparticles and its excellent catalytic activity for Suzuki coupling reaction [J].

Rana, Surjyakanta ;

Maddila, Suresh ;

Yalagala, Kotaiah ;

Jonnalagadda, Sreekantha B. .

APPLIED CATALYSIS A-GENERAL, 2015, 505 :539-547

[45] Graphene oxide (GO) or reduced graphene oxide (rGO): efficient catalysts for one-pot metal-free synthesis of quinoxalines from 2-nitroaniline [J].

Roy, Babli ;

Ghosh, Sujit ;

Ghosh, Pranab ;

Basu, Basudeb .

TETRAHEDRON LETTERS, 2015, 56 (48) :6762-6767

[46] Catalysis for NOx abatement [J].

Roy, Sounak ;

Hegde, M. S. ;

Madras, Giridhar .

APPLIED ENERGY, 2009, 86 (11) :2283-2297

[47] REDOX CHEMISTRY IN EXCESSIVELY ION-EXCHANGED CU/NA-ZSM-5 [J].

SARKANY, J ;

DITRI, JL ;

SACHTLER, WMH .

CATALYSIS LETTERS, 1992, 16 (03) :241-249

[48] Pd-xMo/Al2O3 catalysts for NO reduction by CO [J].

Schmal, M ;

Baldanza, MAS ;

Vannice, MA .

JOURNAL OF CATALYSIS, 1999, 185 (01) :138-151

[49]

SHELEF M, 1971, CHEM ENG PROGR S SER, V67, P74

[50] Trends in NOx abatement: A review [J].

Skalska, Kinga ;

Miller, Jacek S. ;

Ledakowicz, Stanislaw .

SCIENCE OF THE TOTAL ENVIRONMENT, 2010, 408 (19) :3976-3989

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