Unusual alkali metal α- or β-phenyl(trimethylsilyl)amides

被引：39

作者：

Antolini, F ^{[1
]}

Hitchcock, PB ^{[1
]}

Lappert, MF ^{[1
]}

Merle, P ^{[1
]}

机构：

[1] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 14期

关键词：

D O I：

10.1039/b003169k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis (1-3 and 5) and structures (1-5) of the crystalline, hydrocarbon-soluble metal amides [M{mu-N(SiMe3)(SiMe2Ph)}(NCBut)(n)](2) [n = 0 and M = Li 1 (cis), M = Na 2 (trans) having intermolecular Na ... C contacts, or n = 1 and M = Na (cis) 3], [Li{mu-N(SiMe3)Ph}-cis](2)[mu-{N(SiMe3)Ph}Li-cis](2) 4 and trans-[Na{mu-N(SiMe3)Ph}(tmen)] 5 are reported.

引用

页码：1301 / 1302

页数：2

共 16 条

[1] X-ray crystallographic studies and comparative reactivity studies of a sodium diisopropylamide (NDA) complex and related hindered amides [J].

Andrews, PC ;

Barnett, NDR ;

Mulvey, RE ;

Clegg, W ;

ONeil, PA ;

Barr, D ;

Cowton, L ;

Dawson, AJ ;

Wakefield, BJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 518 (1-2) :85-95

[2]

ANDRIANOV KA, 1966, ZH OBSHCH KHIM+, V36, P895

[3]

ANTOLINI F, UNPUB

[4]

ATWOOD JL, UNPUB

[5] 3 MODEL STRUCTURAL TYPES IN LITHIUM AMIDE CHEMISTRY - THE CRYSTAL AND MOLECULAR-STRUCTURES OF DIMERIC [PH(ME)NLI.ME2NCH2CH2NME2]2 AND MONOMERIC PH(NAPHTHYL)NLI.MEN(CH2CH2NME2)2 AND OF [PH(NAPHTHYL)NLI.TMEDA]2, A LOOSE DIMER [J].

BARR, D ;

CLEGG, W ;

MULVEY, RE ;

SNAITH, R ;

WRIGHT, DS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (10) :716-718

[6] [TERT-BUTYLCYANIDE.LITHIUM BIS(TRIMETHYLSILYL)-AMIDE]2, A MODEL OF THE INTERMEDIATE RCN.MR' COMPLEX FORMED IN REACTIONS OF CYANIDES RCN WITH ORGANOMETALLIC COMPOUNDS R'M [J].

BOCHE, G ;

LANGLOTZ, I ;

MARSCH, M ;

HARMS, K ;

FRENKING, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (08) :1171-1173

[7] Synthesis and crystal structure of the tris(amide) cations [M{N(SiMe3)2}3]+ (M = Zr or Hf):: evidence for M-Si-C interactions [J].

Galsworthy, JR ;

Green, MLH ;

Maxted, N ;

Muller, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (03) :387-392

[8] Synthesis and crystal structure of trimeric sodium 2,2,6,6-tetramethylpiperidide (NaTMP) [J].

Gehrhus, B ;

Hitchcock, PH ;

Kennedy, AR ;

Lappert, MF ;

Mulvey, RE ;

Rodger, PJA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 587 (01) :88-92

[9] STRUCTURES OF ORGANONITROGEN LITHIUM COMPOUNDS - RECENT PATTERNS AND PERSPECTIVES IN ORGANOLITHIUM CHEMISTRY [J].

GREGORY, K ;

SCHLEYER, PV ;

SNAITH, R .

ADVANCES IN INORGANIC CHEMISTRY, 1991, 37 :47-142

[10] SYNTHESIS AND MOLECULAR-STRUCTURE OF THE SOLVENT-FREE [LIN(SIME3)(2,6-ISO-PR2C6H3)]2 DIMER [J].

KENNEPOHL, DK ;

BROOKER, S ;

SHELDRICK, GM ;

ROESKY, HW .

CHEMISCHE BERICHTE, 1991, 124 (10) :2223-2225

← 1 2 →