[(arene)Rh(cod)]+ complexes as catalysts for [5+2] cycloaddition reactions

被引：0
|
作者：
Wender, PA [1 ]
Williams, TJ [1 ]
机构：
[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 23期
关键词：
arene ligands; cycloaddition; homogeneous catalysis; medium-sized rings; rhodium;
D O I：
10.1002/1521-3773(20021202)41:23<4550::AID-ANIE4550>3.0.CO;2-D
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Within a few minutes at room temperature, intramolecular [5+2] cycloaddition reactions of vinylcyclopropanes and tethered alkenes or alkynes reach completion when arene-ligated rhodium(I) complexes are used as catalysts (see scheme). In particular, naphthalene complex 1 was found to be an exceptionally effective and, in cases where comparisons have been made, preferred catalyst.
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页码：4550 / +
页数：5
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