A novel route to the synthesis of PP-g-PMMA copolymer via ATRP reaction initiated by Si-Cl bond

被引：16

作者：

Li, Huayi ^{[1
]}

Zhao, Haihuan ^{[1
]}

Zhang, Xiaofan ^{[1
]}

Lu, Yingying ^{[1
]}

Hu, Youliang ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China

来源：

EUROPEAN POLYMER JOURNAL | 2007年 / 43卷 / 01期

基金：

中国国家自然科学基金;

关键词：

polypropylene; functionalization; allyldimethylsilane; copolymerization; Ziegler-Natta catalyst; coordination polymerization; ATRP; graft copolymer;

D O I：

10.1016/j.eurpolymj.2006.10.010

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The copolymerization of propylene with allyldimethylsilane (ADMS) was carried out with conventional Ziegler-Natta catalyst supported on MgCl2. The effects of the concentration of ADMS in the feed on the polymerization reaction and copolymer properties were investigated. The resulting copolymer PP-co-ADMS was chlorinated to PP-Si-Cl by refluxing the copolymer with SOCl2 in benzene. The chlorinated copolymer was used to initiate ATRP of MMA with CuCl/PMDETA as catalyst to produce graft copolymer PP-g-PMMA, which was characterized with H-1 NMR, C-13 NMR, GPC and DSC. Polymer blend of iPP/PP-g-PMMA/PMMA was prepared and the results shown that PP-g-PMMA was an effective compatilizer. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：109 / 118

页数：10

共 19 条

[1] RADIATION CROSS-LINKING OF PROPYLENE-VINYLSILANE COPOLYMER [J].