A Breathing Zirconium Metal-Organic Framework with Reversible Loss of Crystallinity by Correlated Nanodomain Formation

被引：46

作者：

Bueken, Bart ^{[1
]}

Vermoortele, Frederik ^{[1
]}

Cliffe, Matthew J. ^{[2
,7
]}

Wharmby, Michael T. ^{[3
,4
]}

Foucher, Damien ^{[5
]}

Wieme, Jelle ^{[6
]}

Vanduyfhuys, Louis ^{[6
]}

Martineau, Charlotte ^{[5
]}

Stock, Norbert ^{[3
]}

Taulelle, Francis ^{[5
]}

Van Speybroeck, Veronique ^{[6
]}

Goodwin, Andrew L. ^{[2
]}

De Vos, Dirk ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, Celestijnenlaan 200F,POB 2461, B-3001 Leuven, Belgium

[2] Univ Oxford, Inorgan Chem Lab, S Parks Rd, Oxford OX1 3QR, England

[3] CAU Kiel, Inst Anorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany

[4] Diamond Light Source, Harwell Sci & Innovat Campus, Didcot OX11 0DE, Oxon, England

[5] Univ Versailles, Inst Lavoisier, UMR CNRS 8180, Ave Etats Unis 45, F-78035 Versailles, France

[6] Univ Ghent, Ctr Mol Modeling, Technol Pk 903, B-9052 Zwijnaarde, Belgium

[7] Univ Cambridge, Dept Chem, Lensfield Rd, Cambridge CB2 1EW, England

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 10期

基金：

欧洲研究理事会; 英国工程与自然科学研究理事会;

关键词：

dynamic porosity; metal-organic frameworks; phase transitions; structure elucidation; zirconium; STABILITY; CLUSTERS; MOFS;

D O I：

10.1002/chem.201600330

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The isoreticular analogue of the metal-organic framework UiO-66(Zr), synthesized with the flexible trans-1,4-cyclohexanedicarboxylic acid as linker, shows a peculiar breathing behavior by reversibly losing long-range crystalline order upon evacuation. The underlying flexibility is attributed to a concerted conformational contraction of up to two thirds of the linkers, which breaks the local lattice symmetry. X-ray scattering data are described well by a nanodomain model in which differently oriented tetragonal-type distortions propagate over about 7-10 unit cells.

引用

页码：3264 / 3267

页数：4

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