Unique ZnS nanobuns decorated with reduced graphene oxide as an efficient and low-cost counter electrode for dye-sensitized solar cells

被引:18
作者
Yin, Jie [1 ]
Wang, Jie [1 ]
Li, Huaiyong [1 ]
Ma, Huiyan [1 ]
Li, Wenzhi [1 ]
Shao, Xin [1 ]
机构
[1] Liaocheng Univ, Coll Mat Sci & Engn, Liaocheng 252059, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
dye-sensitized solar cells; counter electrode; reduced graphene oxide; ZnS; synergetic effect; nanocomposite;
D O I
10.1016/S2095-4956(14)60185-6
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Unique ZnS nanobuns decorated with reduced graphene oxide (RGO) was synthesized and found to exhibit a synergetic effect as a highly efficient and low-cost counter electrode (CE) in dye-sensitized solar cells (DSCs). Using this ZnS-RGO CE, a power conversion efficiency (PCE) of 7.03% was achieved. This value was 53% and 41% higher than those of pure ZnS and RGO CEs, respectively. The ZnS-RGO nanocomposite is indeed an efficient and cost-effective Pt-like alternative for iodine reduction reaction.
引用
收藏
页码:559 / 563
页数:5
相关论文
共 15 条
[1]   Honeycomb Carbon: A Review of Graphene [J].
Allen, Matthew J. ;
Tung, Vincent C. ;
Kaner, Richard B. .
CHEMICAL REVIEWS, 2010, 110 (01) :132-145
[2]   Synthesis of graphene-CoS electro-catalytic electrodes for dye sensitized solar cells [J].
Das, Santanu ;
Sudhagar, P. ;
Nagarajan, S. ;
Ito, Eisuke ;
Lee, Sang Yun ;
Kang, Yong Soo ;
Choi, Wonbong .
CARBON, 2012, 50 (13) :4815-4821
[3]   Recent advances in alternative cathode materials for iodine-free dye-sensitized solar cells [J].
Hao, Feng ;
Dong, Pei ;
Luo, Qiang ;
Li, Jianbao ;
Lou, Jun ;
Lin, Hong .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (07) :2003-2019
[4]   A graphene dispersed CdS-MoS2 nanocrystal ensemble for cooperative photocatalytic hydrogen production from water [J].
Jia, Tiantian ;
Kolpin, Amy ;
Ma, Chensheng ;
Chan, Ruth Chau-Ting ;
Kwok, Wai-Ming ;
Tsang, S. C. Edman .
CHEMICAL COMMUNICATIONS, 2014, 50 (10) :1185-1188
[5]   Electrophoretic deposition of transparent MoS2-graphene nanosheet composite films as counter electrodes in dye-sensitized solar cells [J].
Lin, Jeng-Yu ;
Chan, Chien-Yi ;
Chou, Shu-Wei .
CHEMICAL COMMUNICATIONS, 2013, 49 (14) :1440-1442
[6]   An integrated approach to realizing high-performance liquid-junction quantum dot sensitized solar cells [J].
McDaniel, Hunter ;
Fuke, Nobuhiro ;
Makarov, Nikolay S. ;
Pietryga, Jeffrey M. ;
Klimov, Victor I. .
NATURE COMMUNICATIONS, 2013, 4
[7]   A LOW-COST, HIGH-EFFICIENCY SOLAR-CELL BASED ON DYE-SENSITIZED COLLOIDAL TIO2 FILMS [J].
OREGAN, B ;
GRATZEL, M .
NATURE, 1991, 353 (6346) :737-740
[8]   Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells [J].
Proietti, Eric ;
Jaouen, Frederic ;
Lefevre, Michel ;
Larouche, Nicholas ;
Tian, Juan ;
Herranz, Juan ;
Dodelet, Jean-Pol .
NATURE COMMUNICATIONS, 2011, 2
[9]   Sub-micrometer-sized Graphite As a Conducting and Catalytic Counter Electrode for Dye-sensitized Solar Cells [J].
Veerappan, Ganapathy ;
Bojan, Karunagaran ;
Rhee, Shi-Woo .
ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (03) :857-862
[10]   CoS Supersedes Pt as Efficient Electrocatalyst for Triiodide Reduction in Dye-Sensitized Solar Cells [J].
Wang, Mingkui ;
Anghel, Alina M. ;
Marsan, Benoit ;
Ha, Ngoc-Le Cevey ;
Pootrakulchote, Nuttapol ;
Zakeeruddin, Shaik M. ;
Graetzel, Michael .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (44) :15976-+