New synthetic routes to highly-extended tetrathiafulvalenes

被引：7

作者：

Hudhomme, Pietrick ^{[1
]}

Salle, Marc ^{[1
]}

Gautier, Nicolas ^{[1
]}

Belyasmine, Ahmed ^{[1
]}

Gorgues, Alain ^{[1
]}

机构：

[1] Univ Angers, CNRS, UMR 6200, Lab CIMMA,Grp Synth Organ & Mat Fonct, 2 Bd Lavoisier, F-49045 Angers, France

来源：

ARKIVOC | 2006年

关键词：

tetrathiafulvalene; Magtrieve (TM); Wittig; HWE olefination; pi-conjugation;

D O I：

10.3998/ark.5550190.0007.406

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various synthetic routes to highly extended tetrathiafulvalene (TTF) derivatives are presented. They generally involve a (poly)olefination reaction in the last step, thanks to Wittig-type or Horner-Wadsworth-Emmons (HWE) reactions. Two complementary strategies have been carried out by reacting a (poly)formyl-TTF with a phosphorous (P-ylide or phosphonate) reagent, or on the contrary, by the preparation of (poly)phosphonate-TTF derivatives prone to react with aldehydes. An X-ray structural determination of one of these systems confirms the high pi-extension of such resulting TTF derivatives.

引用

页码：49 / 72

页数：24

共 28 条

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