New synthetic routes to highly-extended tetrathiafulvalenes

被引：7
|
作者：
Hudhomme, Pietrick [1 ]
Salle, Marc [1 ]
Gautier, Nicolas [1 ]
Belyasmine, Ahmed [1 ]
Gorgues, Alain [1 ]
机构：
[1] Univ Angers, CNRS, UMR 6200, Lab CIMMA,Grp Synth Organ & Mat Fonct, 2 Bd Lavoisier, F-49045 Angers, France
来源：
ARKIVOC | 2006年
关键词：
tetrathiafulvalene; Magtrieve (TM); Wittig; HWE olefination; pi-conjugation;
D O I：
10.3998/ark.5550190.0007.406
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Various synthetic routes to highly extended tetrathiafulvalene (TTF) derivatives are presented. They generally involve a (poly)olefination reaction in the last step, thanks to Wittig-type or Horner-Wadsworth-Emmons (HWE) reactions. Two complementary strategies have been carried out by reacting a (poly)formyl-TTF with a phosphorous (P-ylide or phosphonate) reagent, or on the contrary, by the preparation of (poly)phosphonate-TTF derivatives prone to react with aldehydes. An X-ray structural determination of one of these systems confirms the high pi-extension of such resulting TTF derivatives.
引用
收藏
页码：49 / 72
页数：24
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