Drying induced phase separation in poly(styrene)-poly(ethylene glycol)-chlorobenzene system

被引:8
作者
Sharma, Jyoti [1 ]
Arya, Raj Kumar [2 ]
Ahuja, Sanjeev [3 ]
机构
[1] Thapar Inst Engn & Technol, Sch Chem & Biochem, Bhadson Rd, Patiala 147004, Punjab, India
[2] Dr BR Ambedkar Natl Inst Technol, Dept Chem Engn, GT Rd Bye Pass, Jalandhar 144011, Punjab, India
[3] Thapar Inst Engn & Technol, Dept Chem Engn, Bhadson Rd, Patiala 147004, Punjab, India
关键词
Multipolymeric membranes; Asymmetric membranes; Solvent casting; Phase separation; Layer-by-layer coatings; SELF-ORGANIZED HONEYCOMB; COPOLYMER-SOLVENT SYSTEMS; POLYMER-POLYMER-SOLVENT; FILMS; THERMODYNAMICS; DIFFUSION; COATINGS;
D O I
10.1007/s10934-018-0704-2
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The morphological studies of poly(styrene)-poly(ethylene glycol)-chlorobenzene films have been performed using scanning electron microscopy. The average diameter of the holes present in the coatings decreased from 7.68 to 3.74 mu m with the increase in the polymer content from 5 to 10%. The solvent played a major role in forming ordered porous polymer films. Asymmetric membrane formed at different concentrations of the ternary system. The effects of various parameters like polymer mass fraction, initial film thickness, and technique of application, on the pore size and uniformity have been studied. The membranes are formed at different concentrations of the ternary system.
引用
收藏
页码:1043 / 1057
页数:15
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