Synthesis of propylene from renewable allyl alcohol by photocatalytic transfer hydrogenolysis

被引：16

作者：

Caner, Joaquim ^{[1
]}

Liu, Zijun ^{[1
]}

Takada, Yuki ^{[2
]}

Kudo, Akihiko ^{[3
]}

Naka, Hiroshi ^{[1
]}

Saito, Susumu ^{[2
,4
]}

机构：

[1] Nagoya Univ, Res Ctr Mat Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] Nagoya Univ, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[3] Tokyo Univ Sci, Dept Appl Chem, Fac Sci, Shinjuku Ku, Tokyo 1628601, Japan

[4] Nagoya Univ, Inst Adv Res, Chikusa Ku, Nagoya, Aichi 4648601, Japan

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2014年 / 4卷 / 11期

关键词：

OXORHENIUM-CATALYZED DEOXYDEHYDRATION; CARBON-DIOXIDE; VISIBLE-LIGHT; HOMOGENEOUS HYDROGENATION; TITANIUM-DIOXIDE; SUGAR ALCOHOLS; EPOXIDATION; METHANOL; TIO2; CO2;

D O I：

10.1039/c4cy00329b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photochemical transformation of biomass-derived or renewable substances with promising scalability is an important challenge for promoting green and sustainable chemistry. We report here that photocatalytic transfer hydrogenolysis of allyl alcohol (obtained from glycerol) gives potentially sustainable propylene with high chemo-and redox selectivity, promoted by powdered Pd/TiO2 in CH3OH (obtained from CO2) under near-ultraviolet-visible light irradiation (lambda > 365 nm) at ambient temperature.

引用

页码：4093 / 4098

页数：6

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