Solvent reorganization as a governing factor in the kinetics of intramolecular dissociative electron transfers. Cleavage of anion radicals of alpha-substituted acetophenones

被引：51
作者：
Andrieux, CP
Saveant, JM
Tallec, A
Tardivel, R
Tardy, C
机构：
[1] UNIV DENIS DIDEROT,ELECTROCHIM MOL LAB,CNRS,UNITE ASSOCIE 438,F-75251 PARIS 05,FRANCE
[2] UNIV RENNES 1,ELECTROCHIM LAB,CNRS,UNITE ASSOCIE 439,F-35042 RENNES,FRANCE
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1996年 / 118卷 / 40期
关键词：
D O I：
10.1021/ja9622564
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[No abstract available]
引用
收藏
页码：9788 / 9789
页数：2
相关论文
共 39 条
[1]   EVIDENCE FOR ORBITAL SYMMETRY RESTRICTIONS IN INTRAMOLECULAR DISSOCIATIVE ELECTRON-TRANSFER [J].
ADCOCK, W ;
ANDRIEUX, CP ;
CLARK, CI ;
NEUDECK, A ;
SAVEANT, JM ;
TARDY, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (31) :8285-8286
[2]   Electrochemistry of electron-transfer probes. The role of the leaving group in the cleavage of radical anions of alpha-aryloxyacetophenones [J].
Andersen, ML ;
Mathivanan, N ;
Wayner, DDM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (20) :4871-4879
[3]   CONTROLLING FACTORS OF STEPWISE VERSUS CONCERTED REDUCTIVE CLEAVAGES - ILLUSTRATIVE EXAMPLES IN THE ELECTROCHEMICAL REDUCTIVE BREAKING OF NITROGEN HALOGEN BONDS IN AROMATIC N-HALOSULTAMS [J].
ANDRIEUX, CP ;
DIFFERDING, E ;
ROBERT, M ;
SAVEANT, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (15) :6592-6599
[4]   ELECTRON-TRANSFER AND BOND BREAKING - EXAMPLES OF PASSAGE FROM A SEQUENTIAL TO A CONCERTED MECHANISM IN THE ELECTROCHEMICAL REDUCTIVE CLEAVAGE OF ARYLMETHYL HALIDES [J].
ANDRIEUX, CP ;
LEGORANDE, A ;
SAVEANT, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (17) :6892-6904
[5]   DETERMINATION OF FORMAL POTENTIALS OF CHEMICALLY UNSTABLE REDOX COUPLES BY 2ND-HARMONIC ALTERNATING-CURRENT VOLTAMMETRY AND CYCLIC VOLTAMMETRY - APPLICATION TO THE OXIDATION OF THIOPHENOXIDE IONS [J].
ANDRIEUX, CP ;
HAPIOT, P ;
PINSON, J ;
SAVEANT, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (17) :7783-7788
[6]  
ANDRIEUX CP, 1986, ELECTROCHEMICAL RE 2, V6, P305
[7]   Thermodynamic control in ion radical cleavages through out-of-cage diffusion of products. Dynamics of C-C fragmentation in cation radicals of tert-butylated NADH analogues and other ion radicals [J].
Anne, A ;
Fraoua, S ;
Moiroux, J ;
Saveant, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (16) :3938-3945
[8]   ELECTRON-TRANSFER QUENCHING OF EXCITED DIPHENYLMETHYL RADICALS [J].
ARNOLD, BR ;
SCAIANO, JC ;
MCGIMPSEY, WG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (25) :9978-9982
[9]   INTRAMOLECULAR ELECTRON-TRANSFER AND DEHALOGENATION OF NITROAROMATIC ANION RADICALS [J].
BAYS, JP ;
BLUMER, ST ;
BARALTOSH, S ;
BEHAR, D ;
NETA, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (03) :320-324
[10]   INTRAMOLECULAR ELECTRON-TRANSFER AND DEHALOGENATION OF ANION RADICALS .4. HALOACETOPHENONES AND RELATED-COMPOUNDS [J].
BEHAR, D ;
NETA, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (09) :2280-2283
1234