Aromatic triazoles as corrosion inhibitors for mild steel in acidic environments

被引:90
作者
Quraishi, MA [1 ]
Sardar, R [1 ]
机构
[1] Aligarh Muslim Univ, Fac Engn & Technol, Dept Appl Chem, Corros Res Lab, Aligarh 202002, Uttar Pradesh, India
关键词
acidic environments; aromatic triazoles; concentration; hydrochloric acid; inhibitors; immersion time; mild steel; potentidynamic polarization; sulfuric acid; temperature; weight loss;
D O I
10.5006/1.3277657
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
3-hydroxyphenyl-4-phenyl-5-mercapto-1,2,4,triazole (HPMT): 3-aminophenyl-4-phenyl-5-mereapto-1,2,4,triazole (APMT), 3,4-diphenyL-5-mercapto-1,2,4-triazole (DPMT); and 3-cinnamyl-4-phenyL-5-mercapto-1,2,4,triazole (CPMT) were synthesized in the laboratory, and their influence on the inhibition of corrosion of mild steel in IN hydrochloric acid (HCl) and 1 N sulfuric acid (H2SO4) was investigated by weight loss and potentiodynamic polarization techniques. The inhibition efficiency of these compounds was found to vary with concentration, temperature, and immersion time, Good inhibition efficiency was evidenced in both acid solutions. The adsorption of these compounds on the steel surface for both acids was found to obey Temkin's adsorption isotherm. The potentiodynamic polarization data showed that the compounds studied were filming (adsorption) inhibitors.
引用
收藏
页码:748 / 755
页数:8
相关论文
共 21 条
[1]   Application of the kinetic-thermodynamic model for inhibition of acid corrosion of steel by inhibitors containing sulfur and nitrogen [J].
AbdElNabey, BA ;
Khamis, E ;
Ramadan, MS ;
ElGindy, A .
CORROSION, 1996, 52 (09) :671-679
[2]  
ALANDIS N, 1995, CORROS PREVENT CONTR, V42, P13
[3]  
ASTM, 1990, ASTM, G.31-72,
[4]  
Barannik S.B., 1960, METAL CORROSION INHI, P31
[5]  
DANLATA CD, 1989, J OIL TECH ASS INDIA, V21, P27
[6]   Some nonionic surfactants as inhibitors of the corrosion of iron in acid chloride solutions [J].
Elachouri, M ;
Hajji, MS ;
Salem, M ;
Kertit, S ;
Aride, J ;
Coudert, R ;
Essassi, E .
CORROSION, 1996, 52 (02) :103-108
[7]  
IQBAL M, 1984, J OIL TECH ASS INDIA, V16, P49
[8]  
MATHUR PB, 1982, CORROSION, V38, P7
[9]   Synergistic influence of iodide ions on the inhibition of corrosion of mild steel in sulphuric acid by n-hexyl amine [J].
Muralidharan, S ;
Azim, SS ;
Berchmans, LJ ;
Iyer, SVK .
ANTI-CORROSION METHODS AND MATERIALS, 1997, 44 (01) :30-&
[10]   The influence of N-heterocyclics on corrosion inhibition and hydrogen permeation through mild steel in acidic solutions [J].
Muralidharan, S ;
Iyer, SV .
ANTI-CORROSION METHODS AND MATERIALS, 1997, 44 (02) :100-&