Structure and stability of H+ associates of (5,10,15,20-tetraphenylporphinato)silver(II) in trifluoroacetic acid

被引：3

作者：

Bichan, N. G. ^{[1
]}

Tyulyaeva, E. Yu. ^{[1
]}

Lomova, T. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Krestov Inst Solut Chem, Ivanovo 153045, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2014年 / 88卷 / 08期

基金：

俄罗斯基础研究基金会;

关键词：

metalloporphyrin; silver; formation of H+ associates; stability; H-1 NMR spectroscopy; BASE INTERACTIONS; COMPLEXES; AZAPORPHYRINS; PORPHYRIN; CRYSTAL; STATE;

D O I：

10.1134/S003602441408007X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Direct experimental confirmation of the formation of ion-molecular associates of (5,10,15,20-tetraphenyl-21H,23H-porphinato)silver(II) (AgTPP) with solvent protons in CF3COOH is obtained by means of 1H NMR spectroscopy. Their structure and spectral properties, as well as the kinetics of dissociation on metal-nitrogen bonds, depending on the concentration of CF3COOH (89-100%) and temperature (298-328 K), are studied It is shown that AgTPP acts as a C-base during the formation of H+ associates, the coordination centers of which have a high stability.

引用

页码：1345 / 1350

页数：6

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