Temperature-controlled formation of two Zn(II)-coordination polymers based on flexible o-phenylenediacetic acid and rigid 1,4-bis(imidazol-1-yl)benzene

被引：13

作者：

Sezer, Gunes Gunay ^{[1
,2
]}

Yesilel, Okan Zafer ^{[1
]}

Arici, Mursel ^{[1
]}

Erer, Hakan ^{[1
]}

机构：

[1] Eskisehir Osmangazi Univ, Dept Chem, Fac Arts & Sci, TR-26480 Eskisehir, Turkey

[2] Bartin Univ, Vocat Sch Hlth Serv, Bartin, Turkey

来源：

POLYHEDRON | 2015年 / 102卷

关键词：

o-Phenylenediacetate; Coordination polymer; Temperature effect; Photoluminescence; 1,4-Bis(imidazol-1-yl)benzene; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; CARBON-DIOXIDE; COMPLEXES; LIGANDS; SERIES; 3D; THIOPHENE-2,5-DICARBOXYLATE;

D O I：

10.1016/j.poly.2015.09.067

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new coordination polymers with the same components, namely [Zn(mu-opda)(mu-dib)(0.5)(dib)](n) (1) and [Zn(mu(3)-opda)(mu-dib)(0.5)] (2), were synthesized under different temperatures and characterized by elemental analyses, IR spectroscopy, powder and single X-ray diffractions. The X-ray results showed that complex 1, synthesized at 120 degrees C, was a 1D ladder-like coordination polymer. When the reaction temperature was increased from 120 to 170 degrees C, a 2D coordination polymer (complex 2) was obtained with the sql topology. The o-pda ligand displayed different coordination modes in 1 and 2. Moreover, thermal, photoluminescence and topological properties of the synthesized complexes were studied in detail. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：514 / 520

页数：7

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