A new 3D rtl-type Cd(II) framework constructed from 1,3,5-benzenetricarboxylic acid: Urothermal synthesis, crystal structure, and photoluminescent property

被引：2
|
作者：
Dong, Yanli [1 ]
Zhang, Li [2 ]
Zhang, Yan [2 ]
机构：
[1] Agr Univ Hebei, Coll Sci, Baoding, Hebei, Peoples R China
[2] Hengshui Univ, Dept Appl Chem, Hengshui 053000, Hebei, Peoples R China
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2017年 / 47卷 / 01期
关键词：
Cd(II) compound; urothermal synthesis; trinuclear subunit; luminescence; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; TOPOLOGIES; DESIGN; SERIES; UNITS;
D O I：
10.1080/15533174.2016.1149721
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Cd(II) compound, namely [Cd-3(BTC)(2)(e-urea)(4)](n) (1 H3BTC = 1,3,5-benzenetricarboxylic acid, e-urea = ethylene urea), has been synthesized by the urothermal reactions of 1,3,5-benzenetricarboxylic acid and Cd(NO3)(2) and further characterized by elemental analysis, powder X-ray diffraction, and single-crystal X-ray diffraction. Compound 1 features a three-dimensional (3D) framework based on trinuclear [Cd-3(COO)(6)(e-urea)(2)] subunits. By viewing BTC3-, trinuclear [Cd-3(COO)(6)(e-urea)(2)] subunits as 3-and 6-connected nodes, respectively, the whole framework of 1 can be simplified into a rtl-type topological network. Moreover, the thermal stability and luminescent property of compound 1 were also investigated.
引用
收藏
页码：73 / 77
页数：5
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