Nickel complex-mediated polymerization of unsymmetrically bis(chlorobenzoylated) 2,2′-dimethoxybiphenyl

被引：13
作者：
Maeyama, K [1 ]
Kinuno, T
Jobashi, T
Yonezawa, N
机构：
[1] Tokyo Univ Agr & Technol, Dept Organ & Polymer Mat Chem, Tokyo 1848588, Japan
[2] Gunma Univ, Dept Chem, Kiryu, Gumma 3768515, Japan
来源：
REACTIVE & FUNCTIONAL POLYMERS | 2004年 / 59卷 / 02期
关键词：
2,2 '-dimethoxybiphenylene units; nickel complex-mediated aromatic coupling reaction; unsymmetrical monomer; heat resistibility; good solubility;
D O I：
10.1016/j.reactfunctpolym.2004.01.005
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Unsymmetrically bis(chlorobenzoylated) 2,2'-dimethoxybiphenyl (7) has been successfully prepared via 4-chlorobenzoylation of 2-bromoanisole, Suzuki coupling of the resulting benzophenone, and 3-chlorobenzoylation of the coupling product. Nickel complex-mediated aromatic coupling polymerization of the obtained unsymmetrically bis(chlorobenzoylated) monomer (7) readily affords the wholly aromatic polyketone having a sufficiently high molecular weight and good solubility in organic solvent, such as chloroform. The alignment of the polyketone (6) is disclosed to be random on the basis of the H-1 NMR spectrum. (C) 2004 Elsevier B.V. All rights reserved.
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收藏
页码：155 / 162
页数：8
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