Metal Coordination Mediated Reversible Conversion between Linear and Cross-Linked Supramolecular Polymers

被引:415
作者
Wang, Feng [1 ]
Zhang, Jinqiang [1 ]
Ding, Xia
Dong, Shengyi [1 ]
Liu, Ming [1 ]
Zheng, Bo [1 ]
Li, Shijun [1 ]
Wu, Ling [1 ]
Yu, Yihua [2 ]
Gibson, Harry W. [3 ]
Huang, Feihe [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
[2] E China Normal Univ, Dept Phys, Shanghai Key Lab Magnet Resonance, Shanghai 200062, Peoples R China
[3] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA
基金
中国国家自然科学基金;
关键词
host-guest systems; metal-ligand coordination; polymers; supramolecular chemistry; topochemistry; MOLECULAR-RECOGNITION; SELF-ORGANIZATION; COMBINATION; CHEMISTRY; PARAQUAT; DYNAMICS; GELS; POLYMERIZATION; COMPLEXATION; SELECTIVITY;
D O I
10.1002/anie.200906389
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) The dynamic duo: Different topologies of dynamic supramolecular polymers, such as linear (see picture, left) and crosslinked species (right), can be reversibly interconverted by external stimuli that utilize host-guest and metal-ligand noncovalent recognition motifs. © 2010 Wiley-VCH Verlag GmbH & Co. KCaA.
引用
收藏
页码:1090 / 1094
页数:5
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