Unexpected reduction pathway of a Co2+ salt to [HCo(CO)4] via [Co2(CO)8] in an ionic liquid

被引：8
作者：
Hebrard, Frederic
Kalck, Philippe
Saussine, Lucien
Magna, Lionel
Olivier-Bourbigou, Helene
机构：
[1] Ecole Natl Super Ingn Arts Chim & Technol, Lab Catalyse Chim Fine & Polymeres, F-31077 Toulouse 4, France
[2] Inst Francais Petr, F-69390 Vernaison, France
来源：
DALTON TRANSACTIONS | 2007年 / 02期
关键词：
Cobalt compounds;
D O I：
10.1039/b616169n
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In the 1-butyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl)amide ionic liquid ([BMI][NTf2]), [Co(NTf2)(2)] is reduced under 5.5 MPa of H-2-CO to [Co-2(CO)(8)] prior to [HCo(CO)(4)], provided a pyridine ligand is present in the medium.
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页码：190 / 191
页数：2
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