Allenylmethylsilanes as nucleophiles in N-acyliminium ion chemistry

被引：40

作者：

Mentink, G ^{[1
]}

van Maarseveen, JH ^{[1
]}

Hiemstra, H ^{[1
]}

机构：

[1] Univ Amsterdam, Inst Mol Chem, NL-1018 WS Amsterdam, Netherlands

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 20期

关键词：

D O I：

10.1021/ol026615d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Treatment of a variety of N-acyliminium ion precursors with 2,3-butadienyl(trimethyl)si lane and related allenes in the presence of SF3-OEt2 provides good yields of N-protected 2-(aminomethyl)-substituted 1,3-dienes, which prove to be useful substrates for subsequent Diels-Alder and alkene metathesis reactions.

引用

页码：3497 / 3500

页数：4

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