{ReIIICl3} core complexes with bifunctional single amino acid chelates

被引：19
作者：
Banerjee, SR
Wei, LH
Levadala, MK
Lazarova, N
Golub, VO
O'Connor, CJ
Stephenson, KA
Valliant, JF
Babich, JW [1 ]
Zubieta, J
机构：
[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA
[2] Biostream Inc, Cambridge, MA 02142 USA
[3] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA
[4] McMaster Univ, Dept Chem, Hamilton, ON L8S 4M1, Canada
来源：
INORGANIC CHEMISTRY | 2002年 / 41卷 / 22期
关键词：
D O I：
10.1021/ic020391d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of the Re(V) starting material [ReO(PPh3)(2)Cl-3] with ligands of the type XN(Y)Z [X = Y = 2-pyridylmethyl, Z = -CH2CO2Et ((LEt)-Et-1), -CH2CH2CO2Et ((LEt)-Et-2), -CH2CH2CH2CH2CH(NHCO2But)CO2H ((LH)-H-3); X = 2-pyridylmethyl, Y = 2-(1-methylimidazolyl)methyl, Z = -CH2CO2Et (L4Et)] yielded the Re(III) trichloride complexes of the type [ReCl3((LR)-R-n)]. The complexes are mononuclear, paramagnetic species with a facial geometry of the chloride ligands. The nitrogen donors of the tridentate (LR)-R-n ligands complete the distorted octahedral coordination spheres of the complexes. Crystal data: [ReCl3((LEt)-Et-1)] (1), monoclinic, C2/m, a = 16.088(3) Angstrom, b = 9.980(2) Angstrom, c = 12.829(2) Angstrom, beta = 91.384(3), Z= 4, D-calc, = 1.967 g/cm(-3); [ReCl3((LEt)-Et-4)] (4), monoclinic, C2/c, a = 22.880(1) Angstrom, b = 7.4926(4) A, c = 22.560(1) Angstrom, beta = 94.186(1)degrees, Z = 8, D-calc = 2.001 g/cm(-3).
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页码：5795 / 5802
页数：8
相关论文
共 56 条
[1]   Contemporary methods for peptide and protein synthesis [J].
Aimoto, S .
CURRENT ORGANIC CHEMISTRY, 2001, 5 (01) :45-87
[2]  
Atherton E., 1989, SOLID PHASE PEPTIDE
[3]   6-mercaptomethylpyridine-3-carboxylic acid (MEMNIC): a new reagent for peptide labeling with Tc-99m [J].
Babich, JW ;
Graham, W ;
Femia, FJ ;
Dong, Q ;
Barzana, M ;
Ferrill, K ;
Fischman, AJ ;
Zubieta, J .
INORGANICA CHIMICA ACTA, 2001, 323 (1-2) :23-36
[4]   99mTc-labeled chemotactic peptides:: influence of coligand on distribution of molecular species and infection imaging properties.: Synthesis and structural characterization of model complexes with the {Re(η2-HNNC5H4N)(η1-NNC5H4N)} core [J].
Babich, JW ;
Coco, WG ;
Barrow, S ;
Fischman, AJ ;
Femia, FJ ;
Zubieta, J .
INORGANICA CHIMICA ACTA, 2000, 309 (1-2) :123-136
[5]   Structural overview of technetium compounds (1993-1999) [J].
Bandoli, G ;
Dolmella, A ;
Porchia, M ;
Refosco, F ;
Tisato, F .
COORDINATION CHEMISTRY REVIEWS, 2001, 214 :43-90
[6]  
Barrett GC., 1998, AMINO ACIDS PEP PROT, DOI [DOI 10.1017/CBO9781139163828, 10.1017/CBO9781139163828]
[7]   Rhenium(III) and rhenium(V) complexes stabilized by the potentially tetradentate ligand tris(2-diphenylphosphinoethyl)amine [J].
Bertolasi, V ;
Marchi, A ;
Marvelli, L ;
Rossi, R ;
Bianchini, C ;
de los Rios, I ;
Peruzzini, M .
INORGANICA CHIMICA ACTA, 2002, 327 (01) :140-146
[8]   Synthesis, structure and redox behaviour of facial [ReIIIL(PPh3)Cl3] and its stereoretentive conversion to [ReIVL′(PPh3)Cl3] via metal promoted aldimine→amide oxidation (L = pyridine-2-aldimine; L′ = pyridine-2-carboxamide [J].
Bhattacharyya, S ;
Banerjee, S ;
Dirghangi, BK ;
Menon, M ;
Chakravorty, A .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (02) :155-159
[9]   SYNTHESIS OF 1-(PARA-ISOTHIOCYANATOBENZYL) DERIVATIVES OF DTPA AND EDTA - ANTIBODY LABELING AND TUMOR-IMAGING STUDIES [J].
BRECHBIEL, MW ;
GANSOW, OA ;
ATCHER, RW ;
SCHLOM, J ;
ESTEBAN, J ;
SIMPSON, DE ;
COLCHER, D .
INORGANIC CHEMISTRY, 1986, 25 (16) :2772-2781
[10]   PHOTOCHEMICAL GENERATION OF A REACTIVE RHENIUM(III) OXO COMPLEX AND ITS CURIOUS MODE OF CLEAVAGE OF DIOXYGEN [J].
BROWN, SN ;
MAYER, JM .
INORGANIC CHEMISTRY, 1992, 31 (20) :4091-4100
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