Gas-phase synthesis of ethyl tert-butyl ether (ETBE) on H-ZSM-5 catalyst in continuous fixed-bed and fluidized-bed reactors

被引:17
作者
Alcántara, R [1 ]
Alcántara, E [1 ]
Canoira, L [1 ]
Franco, MJ [1 ]
Martín, I [1 ]
Navarro, A [1 ]
机构
[1] Univ Politecn Madrid, Sch Mines, Dept Chem Engn & Fuels, Madrid 28003, Spain
来源
REACTION KINETICS AND CATALYSIS LETTERS | 2000年 / 69卷 / 02期
关键词
ETBE; H-ZSM-5; gas-phase; fixed-bed; fluidized-bed;
D O I
10.1023/A:1005631313062
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The gas-phase synthesis of ETBE from ethanol and isobutene has been carried out over a H-ZSM-5 catalyst in two types of continuous-flow catalytic reactors, fixed-bed and fluidized-bed. We have studied the influence of temperature, molar ratio ethanol/isobutene and weight hourly space velocity on the yield of ETBE.
引用
收藏
页码:239 / 246
页数:8
相关论文
共 25 条
[1]   Continous flow preparation of methyl tert-butyl ether (MTBE) over ZSM-5 catalyst in fixed-bed and fluidized-bed reactors [J].
Agullo, F ;
Alcantara, R ;
Canoira, L ;
Fernandez-Sanchez, JM ;
Navarro, A ;
Neila, JR .
REACTION KINETICS AND CATALYSIS LETTERS, 1998, 64 (01) :161-167
[2]   AUTOMATION OF A FIXED-BED CONTINUOUS-FLOW REACTOR [J].
ALCANTARA, R ;
CANOIRA, L ;
CONDE, R ;
FERNANDEZSANCHEZ, JM ;
NAVARRO, A .
JOURNAL OF AUTOMATIC CHEMISTRY, 1994, 16 (05) :187-193
[3]   THE INFLUENCE OF OXONIUM ION AND CARBENIUM ION STABILITIES ON THE ALCOHOL/H-ZSM-5 INTERACTION [J].
ARONSON, MT ;
GORTE, RJ ;
FARNETH, WE .
JOURNAL OF CATALYSIS, 1986, 98 (02) :434-443
[4]   EFFECT OF WATER PRESENCE ON METHYL TERT-BUTYL ETHER AND ETHYL TERT-BUTYL ETHER LIQUID-PHASE SYNTHESES [J].
CUNILL, F ;
VILA, M ;
IZQUIERDO, JF ;
IBORRA, M ;
TEJERO, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (03) :564-569
[5]   Tertiary alkyl ethers preparation and properties [J].
Evans, TW ;
Edlund, KR .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1936, 28 :1186-1188
[6]  
FOGLER HS, 1986, ELEMENTS CHEM REACTI, P260
[7]   Experimental study of the simultaneous synthesis of methyl tert-butyl ether and ethyl tert-butyl ether in liquid phase [J].
Gomez, C ;
Cunill, F ;
Iborra, M ;
Izquierdo, F ;
Tejero, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1997, 36 (11) :4756-4762
[8]  
IBORRA M, 1988, CHEMTECH FEB, P120
[9]   EQUILIBRIUM-CONSTANTS FOR METHYL TERT-BUTYL ETHER AND ETHYL TERT-BUTYL ETHER LIQUID-PHASE SYNTHESIS USING C(4) OLEFINIC CUT [J].
IZQUIERDO, JF ;
CUNILL, F ;
VILA, M ;
IBORRA, M ;
TEJERO, J .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1994, 33 (11) :2830-2835
[10]  
JACOBY S, 1987, ELR J, V1, P33