Isolation and characterization of two Pr@C82 isomers

被引：79

作者：

Akasaka, T ^{[1
]}

Okubo, S

Kondo, M

Maeda, Y

Wakahara, T

Kato, T

Suzuki, T

Yamamoto, K

Kobayashi, K

Nagase, S

机构：

[1] Niigata Univ, Grad Sch Sci & Technol, Niigata 9502181, Japan

[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

[3] Power Reactor & Nucl Fuel Dev, Tokai, Ibaraki 3191100, Japan

[4] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Tokyo 1920397, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2000年 / 319卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(00)00120-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The second isomer of Pr@C-82 (Pr@C-82-II) has been isolated by a two-step HPLC method, separately from the known major isomer (Pr@C-82-I). Visible and near-IR absorption spectra, as well as cyclic and differential pulse voltammograms show that the characteristic features of Pr@C-82-II are significantly different from those of Pr@C-82-I. The absorption peaks of Pr@C-82-II have blue-shifts and the redox potentials have negative shifts, relative to those of Pr@C-82-I. Chemical derivatization of both isomers with disilirane have also been achieved. (C) 2000 Published by Elsevier Science B.V. All rights reserved.

引用

页码：153 / 156

页数：4

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