The authors have fabricated combinatorial Ni-Ti-Pt ternary metal gate thin film libraries on HfO2 using magnetron co-sputtering to investigate flatband voltage shift (Delta V-fb), work function (Phi(m)), and leakage current density (J(L)) variations. A more negative Delta V-fb is observed close to the Ti-rich corner than at the Ni- and Pt-rich corners, implying smaller Phi(m) near the Ti-rich corners and higher Phi(m) near the Ni- and Pt-rich corners. In addition, measured J(L) values can be explained consistently with the observed Phi(m) variations. Combinatorial methodologies prove to be useful in surveying the large compositional space of ternary alloy metal gate electrode systems. (c) 2006 American Institute of Physics.