Synthesis and properties of novel eugenol-based polymers

被引：7
|
作者：
Rahim, EA [1 ]
Sanda, F [1 ]
Masuda, T [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Kyoto 6158510, Japan
来源：
POLYMER BULLETIN | 2004年 / 52卷 / 02期
关键词：
D O I：
10.1007/s00289-004-0272-2
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This work deals with the synthesis and characterization of novel eugenol-based polymers. The polymerization of 2-methoxy-4-propenyl-1-prop-2-ynyloxybenzene (1) with Rh, Mo, and W catalysts gave the corresponding polyacetylene [poly(1)], while that using BF3 catalyst gave poly(1)', without affecting the triple bond. A novel cross-linked polyacetylene was synthesized from poly (1)' with [(nbd)RhC1](2)-Et3N catalyst.
引用
收藏
页码：93 / 100
页数：8
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