A Method for Solving the Inverse Problem of Chemical Kinetics for a Nonisothermal Gradientless Reactor Based on Steady-State Data

被引：7
作者：
Kol'tsov, N. I. [1 ]
机构：
[1] Chuvash State Univ, Cheboksary 428015, Chuvash Republi, Russia
来源：
THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING | 2020年 / 54卷 / 05期
关键词：
inverse problem; chemical reactions; rate constants of stages; steady-state kinetics; nonisothermal reactor; PARAMETERS; NUMBER; MODELS;
D O I：
10.1134/S004057952005036X
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A method has been presented for solving the inverse problem of chemical kinetics based on steady-state experimental data with different initial conditions (multiexperiments) taking into account measurement errors in an open nonisothermal gradientless reactor. Examples of using the method to determine the intervals of the physical values of rate constants for the stages of multistage nonlinear reactions have been given. The effect of measurement errors on the accuracy and stability of the method has been evaluated.
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页码：863 / 871
页数：9
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