A one-pot, stereoselective synthesis of 2-ethoxycarbonyl-substituted 1,3-dienes and 1,3-enynes by hydrostannylation - Stille tandem reaction of tributyltin hydride with alkynyl esters and alkenyl or alkynyl halides

被引：6

作者：

Cai, Mingzhong ^{[1
]}

Fang, Xiaoniu ^{[2
]}

Dai, Ruchun

Zha, Lingfang

机构：

[1] Jiangxi Normal Univ, Dept Chem, Sch Chem & Chem Engn, Nanchang 330022, Peoples R China

[2] Jinggangshan Univ, Sch Chem & Chem Engn, Jian 343009, Jiangxi, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2009年 / 23卷 / 06期

基金：

中国国家自然科学基金;

关键词：

hydrostannylation; (E)-alpha-stannyl-alpha; beta-unsaturated esters; Stille coupling; 1,3-diene; 1,3-enyne; CROSS-COUPLING REACTIONS; TRANSITION-METAL CATALYSIS; HIGHLY SELECTIVE SYNTHESIS; DIELS-ALDER REACTION; CONJUGATED DIENES; STEREODEFINED ENYNES; (E)-ALPHA-STANNYLVINYL SULFIDES; STEREOCONTROLLED SYNTHESIS; HYDROMAGNESIATION REACTION; ORGANIC-SYNTHESIS;

D O I：

10.1002/aoc.1502

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

2-Ethoxycarbonyl-substituted 1,3-dienes and 1,3-enynes can be stereoselectively synthesized in one pot under mild conditions, in good yields, by the palladium-catalyzed hydrostannylation of alkynyl esters, followed by Stille coupling with alkenyl or alkynyl halides, respectively. Copyright (C) 2009 John Wiley & Sons, Ltd.

引用

页码：229 / 234

页数：6

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