Hydrothermal synthesis and structure of [(PbCl2)(μ-Pyz)1/2]n (Pyz = pyrazine)

被引：0
作者：
Liao Qiu-Xia [1 ]
Zhang Jian [1 ]
Qin Ye-Yan [1 ]
Yao Yuan-Gen [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2006年 / 25卷 / 07期
关键词：
crystal structure; lead chloride; pyrazine;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel 2-D lead-containing hybrid compound, [(PbCl2)(mu-Pyz)(1/2)](n) (Pyz = pyrazine) 1, has been synthesized by the hydrothermal assembly of pyrazine with lead chloride. Elemental analysis and X-ray crystal structure analyses were carried out for the structural determination and characterization of the title compound. Compound 1 crystallizes in orthorhombic, space group 15am, with a = 19.5558(18), b = 7.1939(6), c = 7.5449(6) angstrom, V = 1061.44(16) angstrom(3), C2H2Cl2NPb, M-r = 318.14, Z = 8, D-c = 3.982 g/cm(3), mu = 32.63 mm(-1), F(000) = 1096.0, R = 0.0368 and wR = 0.0901 for 623 observed reflections (I > 2 sigma(I)).
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收藏
页码：789 / 792
页数：4
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