Anodic oxidation of the N-cyanomethyloxazolidine system.

被引：12

作者：

BillonSouquet, F

Martens, T

Royer, J

机构：

[1] CNRS,INST CHIM SUBST NAT,F-91198 GIF SUR YVETTE,FRANCE

[2] UNIV PARIS 05,FAC PHARM,LAB CHIM ANALYT & ELECTROCHIM,CNRS,F-75782 PARIS 06,FRANCE

来源：

TETRAHEDRON | 1996年 / 52卷 / 48期

关键词：

D O I：

10.1016/S0040-4020(96)00947-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrochemical oxidation of the N-cyanomethyloxazolidine system in acetonitrile at a platinum electrode afforded a radical cation which might follow either one of two pathways, according to the experimental conditions: the first, in the presence of chloride or bromide ions led to halogenated products, the second, in the presence of water, led to lactam/amide formation. The mechanistic pathway of both reactions is discussed. Copyright (C) 1996 Elsevier Science Ltd

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页码：15127 / 15136

页数：10

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