Development of aromatic polyamide membranes for pervaporation and vapor permeation

被引:47
作者
Teng, MY
Lee, KR [1 ]
Fan, SC
Liaw, DJ
Huang, J
Lai, JY
机构
[1] Nanya Jr Coll Technol, Dept Chem Engn, Chungli, Taiwan
[2] Chung Yuan Christian Univ, Dept Chem Engn, Membrane Res lab, Chungli 32023, Taiwan
[3] Natl Taiwan Univ Sci & Technol, Dept Chem Engn, Taipei 10772, Taiwan
[4] Yeu Ming Tai Chem Ind Co Ltd, Taichung 407, Taiwan
关键词
pervaporation; vapor permeation; fluorine-containing aromatic polyamide; membrane;
D O I
10.1016/S0376-7388(99)00206-9
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The pervaporation and vapor permeation performances of a series of fluorine-containing aromatic polyamide membranes for various alcohol mixtures were investigated. Compared with pervaporation, vapor permeation effectively increases the permselectivity of water. The solubility of alcohol in an aromatic membrane is higher than that of water, but the diffusivity of water across the membrane is higher than that of the alcohols. In addition, the relationship between the polymer structure and pervaporation performance was obtained. It was found that the permeation rate can be increased by the introduction of bulky substituted groups and arylene ether groups into the polymer backbone. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:241 / 249
页数:9
相关论文
共 16 条
[1]   PERVAPORATION SEPARATION OF ACETIC-ACID WATER MIXTURES USING MODIFIED MEMBRANES .2. GAMMA-RAY-INDUCED GRAFTED POLYACRYLIC-ACID (PAA) NYLON 6 MEMBRANES [J].
HUANG, RYM ;
XU, YF .
JOURNAL OF MEMBRANE SCIENCE, 1989, 43 (2-3) :143-148
[2]   PREDICTION OF PERVAPORATION SEPARATION CHARACTERISTICS FOR THE METHANOL PENTANE NYLON-6 POLY (ACRYLIC-ACID) BLENDED MEMBRANE SYSTEM [J].
HUANG, RYM ;
RHIM, JW .
JOURNAL OF MEMBRANE SCIENCE, 1992, 71 (03) :211-220
[3]   PERVAPORATION SEPARATION OF ACETIC ACID-WATER MIXTURES USING MODIFIED MEMBRANES .1. BLENDED POLYACRYLIC-ACID (PAA)-NYLON 6 MEMBRANES [J].
HUANG, RYM ;
MOREIRA, A ;
NOTARFONZO, R ;
XU, YF .
JOURNAL OF APPLIED POLYMER SCIENCE, 1988, 35 (05) :1191-1200
[4]  
HUANG RYM, 1980, P 2 INT C SEP SCI TE, V1, P74
[5]  
KOROS WJ, 1992, ANNU REV MATER SCI, V22, P47
[6]   POLYVINYL-ALCOHOL GAMMA-RAY GRAFTED NYLON-4 MEMBRANE FOR PERVAPORATION AND EVAPORATION [J].
LAI, JY ;
CHEN, RY ;
LEE, KR .
SEPARATION SCIENCE AND TECHNOLOGY, 1993, 28 (07) :1437-1452
[7]   PLASMA DEPOSITION OF VINYL-ACETATE ONTO NYLON-4 MEMBRANE FOR PERVAPORATION AND EVAPORATION SEPARATION OF AQUEOUS ALCOHOL MIXTURES [J].
LEE, KR ;
CHEN, RY ;
LAI, JY .
JOURNAL OF MEMBRANE SCIENCE, 1992, 75 (1-2) :171-180
[8]  
Lee KR, 1998, EUR POLYM J, V34, P665
[9]   Selective separation of water from aqueous alcohol solution through fluorine-containing aromatic polyamide membranes by pervaporation [J].
Lee, KR ;
Liaw, DJ ;
Liaw, BY ;
Lai, JY .
JOURNAL OF MEMBRANE SCIENCE, 1997, 131 (1-2) :249-259
[10]  
LEE KR, 1998, UNPUB J MEMBR SCI