Radical polymerization of acrylic monomers: An overview

被引：138

作者：

Ballard, Nicholas ^{[1
]}

Asua, Jose M. ^{[1
]}

机构：

[1] Univ Basque Country, UPV EHU, POLYMAT, Joxe Mari Korta Zentroa, Tolosa Etorbidea 72, Donostia San Sebastian 20018, Spain

来源：

PROGRESS IN POLYMER SCIENCE | 2018年 / 79卷

关键词：

Acrylates; Radical polymerization; Pulsed laser polymerization (PLP); Electron spin resonance (ESR); Branching; N-BUTYL ACRYLATE; PROPAGATION RATE COEFFICIENTS; PULSED-LASER-POLYMERIZATION; INTRAMOLECULAR CHAIN TRANSFER; LENGTH-DEPENDENT TERMINATION; MOLECULAR-WEIGHT DISTRIBUTIONS; SEMIBATCH EMULSION COPOLYMERIZATION; NITROXIDE-MEDIATED POLYMERIZATION; HIGH-TEMPERATURE POLYMERIZATION; EVALUATED RATE COEFFICIENTS;

D O I：

10.1016/j.progpolymsci.2017.11.002

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Since their discovery and development in the 20th century, acrylic polymers have become an integral part of numerous industries and are used in a myriad of applications. As is true for many polymers, the suitability of a particular polyacrylate for a given application comes from its structure, which is determined during its synthesis in the reactor, long before commercial use. Uniquely, the radical polymerization of acrylic monomers is strongly affected by radical transfer events which dictate reaction kinetics and lead to a range of distinct macromolecular structures, a fact that went unknown for many years and continues to generate unexpected results. In this review, we aim to present the current picture of the various competitive processes which occur during polymerization of acrylic monomers, as well as the ongoing issues that hinder our complete comprehension of this complicated monomer family. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：40 / 60

页数：21

共 195 条

[1] Polymerization of n-butyl acrylate with high concentration of a chain transfer agent (CBr4): detailed characterization and impact on branching [J].