Low-energy photoelectron imaging spectroscopy of nitromethane anions: Electron affinity, vibrational features, anisotropies, and the dipole-bound state

被引：49
作者：
Adams, Christopher L.
Schneider, Holger
Ervin, Kent M. [2 ]
Weber, J. Mathias [1 ]
机构：
[1] Univ Colorado, JILA, NIST, Boulder, CO 80309 USA
[2] Univ Nevada, Dept Chem, Reno, NV 89557 USA
来源：
JOURNAL OF CHEMICAL PHYSICS | 2009年 / 130卷 / 07期
基金：
美国国家科学基金会;
关键词：
ab initio calculations; bound states; electron affinity; electron detachment; Franck-Condon factors; molecular moments; negative ions; organic compounds; photoelectron spectra; vibrational states; CORE-CONTRIBUTION CALCULATION; GAUSSIAN-BASIS SETS; NEGATIVE-IONS; CLUSTER ANIONS; PHOTODETACHMENT SPECTROSCOPY; MOLECULAR CALCULATIONS; ANGULAR-DISTRIBUTION; CROSS-SECTIONS; TRIPLET-STATES; DYNAMICS;
D O I：
10.1063/1.3076892
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We present low-energy velocity map photoelectron imaging results for nitromethane anions. The photoelectron spectrum is interpreted with the aid of ab initio theory and Franck-Condon factor calculations. We obtain a new value for the adiabatic electron affinity of nitromethane of (172 +/- 6) meV and observe the dipole-bound state of nitromethane. The photoelectron angular distributions of the observed features are discussed in the context of threshold laws for photodetachment.
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页数：10
相关论文
共 62 条
  • [1] Dissociative electron attachment to nitromethane
    Alizadeh, E.
    da Silva, F. Ferreira
    Zappa, F.
    Mauracher, A.
    Probst, M.
    Denifl, S.
    Bacher, A.
    Maerk, T. D.
    Limao-Vieira, P.
    Scheier, P.
    [J]. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2008, 271 (1-3) : 15 - 21
  • [2] [Anonymous], 2017, J MOL STRUCT, DOI DOI 10.1016/J.MOLSTRUC.2017.03.014
  • [3] DENSITY-FUNCTIONAL THERMOCHEMISTRY .3. THE ROLE OF EXACT EXCHANGE
    BECKE, AD
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) : 5648 - 5652
  • [4] HIGH-RESOLUTION PHOTOELECTRON SPECTROMETRY OF NEGATIVE-IONS - FINE-STRUCTURE TRANSITIONS IN O- AND S- PHOTODETACHMENT
    BREYER, F
    FREY, P
    HOTOP, H
    [J]. ZEITSCHRIFT FUR PHYSIK A-HADRONS AND NUCLEI, 1978, 286 (02): : 133 - 138
  • [5] Chen P., 1994, UNIMOLECULAR BIMOLEC, P371
  • [6] ZERO-CORE-CONTRIBUTION CALCULATION OF A POLYATOMIC PHOTODETACHMENT CROSS-SECTION - NO2-
    CLODIUS, WB
    STEHMAN, RM
    WOO, SB
    [J]. PHYSICAL REVIEW A, 1983, 28 (02): : 760 - 765
  • [7] On the binding of electrons to nitromethane: Dipole and valence bound anions
    Compton, RN
    Carman, HS
    Desfrancois, C
    AbdoulCarmine, H
    Schermann, JP
    Hendricks, JH
    Lyapustina, SA
    Bowen, KH
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1996, 105 (09) : 3472 - 3478
  • [8] ANGULAR DISTRIBUTION OF PHOTOELECTRONS
    COOPER, J
    ZARE, RN
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (02) : 942 - &
  • [9] Spectroscopic observation of vibrational Feshbach resonances in near-threshold photoexcitation of X-•CH3NO2 (X- = I- and Br-)
    Dessent, CEH
    Kim, J
    Johnson, MA
    [J]. FARADAY DISCUSSIONS, 2000, 115 : 395 - 406
  • [10] Reconstruction of abel-transformable images: The Gaussian basis-set expansion abel transform method
    Dribinski, V
    Ossadtchi, A
    Mandelshtam, VA
    Reisler, H
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 2002, 73 (07) : 2634 - 2642
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