Dehydration of xylose to furfural over niobium phosphate catalyst in biphasic solvent system

被引:63
作者
Pholjaroen, Boonrat [1 ,2 ]
Li, Ning [1 ]
Wang, Zhiqiang [1 ,3 ]
Wang, Aiqin [1 ]
Zhang, Tao [1 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Sichuan Univ, Dept Chem Engn, Chengdu 610065, Sichuan, Peoples R China
关键词
xylose; furfural; dehydration; biphasic solvent system; solid acid catalyst; niobium phosphate; LIQUID-PHASE DEHYDRATION; SOLID ACID CATALYSTS; FRUCTOSE DEHYDRATION; SULFATED ZIRCONIA; LEVULINIC ACID; BIOMASS; CONVERSION; HYDROGENATION; ISOMERIZATION; TEMPERATURE;
D O I
10.1016/S2095-4956(14)60260-6
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Phosphoric acid treated niobic acid (NbP) was used for the dehydration of xylose to furfural in biphasic solvent system, which was found to exhibit the best performance among the tested catalysts. The excellent performance of NbP could be explained by the better synergistic cooperation between Bronsted and Lewis acid sites. Moreover, NbP showed good stability and no obvious deactivation or leaching of Nb could be observed after six continuous recycles.
引用
收藏
页码:826 / 832
页数:7
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