Coordination-number dependence of reactivity in an imidoiron(III) complex

被引：138

作者：

Eckert, Nathan A.

Vaddadi, Sridhar

Stoian, Sebastian

Lachicotte, Rene J.

Cundari, Thomas R. ^{[1
]}

Holland, Patrick L.

机构：

[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA

[2] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

[3] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 41期

关键词：

coordination number; hydrogen-atom abstraction; imido ligands; iron;

D O I：

10.1002/anie.200601927

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Reaction of the {LMeFe} fragment with adamantyl azide (AdN3) in the presence of 4-tert-butylpyridine (tBuPy) gives an S = 3/2 species that has been examined by 1H NMR, IR, EPR, and Mössbauer spectroscopies. DFT calculations point toward an identification as [LMeFeNAd]. This species abstracts hydrogen atoms from the ligand or external reagents only through its pyridine adduct (see scheme; Ar = 2,6-iPr2C6H3). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6868 / 6871

页数：4

共 23 条

[1] AN EQUATION OF STATE FROM A NEW COORDINATION-NUMBER MODEL
YU, ML
CHEN, YP
FLUID PHASE EQUILIBRIA, 1995, 111 (01) : 37 - 51
[2] THE COORDINATION-NUMBER OF EQUAL DISKS IN 2-DIMENSIONAL RANDOM PACKING
DONG, Q
YE, DN
CHINESE SCIENCE BULLETIN, 1993, 38 (21): : 1793 - 1797
[3] LIQUID-LIQUID PARTITION OF ZINC ALKANEDIONATES AND ZINC MONOTHIOACETYLACETONATE - THE COORDINATION-NUMBER OF ZINC
NARBUTT, J
POLISH JOURNAL OF CHEMISTRY, 1993, 67 (02) : 293 - 303
[4] C-H activation by a terminal imidoiron(III) complex to form a cyclopentadienyliron(II) product
Cowley, Ryan E.
Holland, Patrick L.
INORGANICA CHIMICA ACTA, 2011, 369 (01) : 40 - 44
[5] ROLE OF PHONON HAVING A CHANGE IN COORDINATION-NUMBER OF VIBRATING ION IN HIGH-TC OXIDE SUPERCONDUCTORS
MOTIDA, K
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1992, 61 (05) : 1465 - 1468
[6] LI-6 NUCLEAR-MAGNETIC-RESONANCE CHEMICAL-SHIFTS, COORDINATION-NUMBER AND RELAXATION IN CRYSTALLINE AND GLASSY SILICATES
XU, Z
STEBBINS, JF
SOLID STATE NUCLEAR MAGNETIC RESONANCE, 1995, 5 (01) : 103 - 112
[7] Structure and Reactivity of a Mononuclear Nonheme Manganese(III)-Iodosylarene Complex
Jeong, Donghyun
Ohta, Takehiro
Cho, Jaeheung
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (47) : 16037 - 16041
[8] Reactivity of a Ru(III)-hydroxo complex in substrate oxidation in water
Ohzu, Shingo
Ishizuka, Tomoya
Kotani, Hiroaki
Kojima, Takahiko
CHEMICAL COMMUNICATIONS, 2014, 50 (95) : 15018 - 15021
[9] Structure and Unprecedented Reactivity of a Mononuclear Nonheme Cobalt(III) Iodosylbenzene Complex
Yang, Jindou
Seo, Mi Sook
Kim, Kyung Ha
Lee, Yong-Min
Fukuzumi, Shunichi
Shearer, Jason
Nam, Wonwoo
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (32) : 13581 - 13585
[10] A Mononuclear Peracetatoiron(III) Complex: Structural and Spectroscopic Characterization, and Oxidation Reactivity
Zhang, Xi
Funitachi, Hideki
Tojo, Tomonori
Tsugawa, Tomohiro
Fujinami, Shuhei
Sakurai, Takeshi
Suzuki, Masatatsu
CHEMISTRY LETTERS, 2011, 40 (05) : 515 - 517

← 1 2 3 →