Haem d(1): stereoselective synthesis of the reduced form of its parent macrocycle using the original coupling strategy

被引：16

作者：

Aucken, CJ ^{[1
]}

Leeper, FJ ^{[1
]}

Battersby, AR ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 14期

关键词：

D O I：

10.1039/a700652g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A substituted isobacteriochlorin, which corresponds structurally to the reduced metal-free macrocycle of haem d(1), has been synthesised by a stereoselective route in which the final step is a photochemical 18 pi-electron antarafacial cyclisation of an open-chain precursor.

引用

收藏

页码：2099 / 2109

页数：11

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