Ag Doped Titanium Dioxide Nanocomposite-modified Glassy Carbon Electrode as Electrochemical Interface for Catechol Sensing

被引:8
|
作者
Ravishankar, T. N. [1 ,2 ]
Kumar, K. Suresh [1 ]
Teixeira, S. R. [2 ]
Fernandez, C. [3 ]
Ramakrishnappa, T. [1 ,4 ]
机构
[1] Jain Univ, Ctr Nano & Mat Sci, Jain Global Campus, Bangalore 560001, Karnataka, India
[2] Univ Fed Rio Grande do Sul, Lab Thin Films & Nanostruct Fabricat L3Fnano, Inst Phys, Ave Bento Toncalves 9500,POB 15051, BR-91501970 Porto Alegre, RS, Brazil
[3] Robert Gordon Univ, Sch Pharm & Life Sci, Garthdee Rd, Aberdeen AB10 7GJ, Scotland
[4] Dayananda Sagar Acad Technol & Management, Kanakapura Rd, Bangalore 560082, Karnataka, India
关键词
Ag doped TiO2 nanoparticles; electrocatalytic activity; catechol; NANOPARTICLES; COMPOSITE; HYDROQUINONE; RESORCINOL; FILM;
D O I
10.1002/elan.201500238
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The electrochemical sensing of catechol (CC) on a glassy carbon electrode modified with the ionothermal assisted synthesis of Ag doped TiO2 a nanoparticle has been successfully demonstrated for the first time.Ag doped TiO2 nanoparticles composite modified glassy carbon electrode exhibits higher electrocatalytic activity towards oxidation of catechol than glassy carbon electrode itself. The modified electrode also exhibits high selectivity towards this analyte in the presence of some of the metal ions and some of the biological compounds. Linear ranges and the limit of detections with the above electrode are 1-15 mu M and 0.0249 mu M respectively. The optimized protocol has been utilized for monitoring the catechol in some of the natural samples like apple juice and green tea and in industrial effluents.
引用
收藏
页码:452 / 461
页数:10
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