Two-Dimensional Graphene Bridges Enhanced Photoinduced Charge Transport in Dye-Sensitized Solar Cells

被引:863
作者
Yang, Nailiang [1 ,2 ]
Zhai, Jin [1 ,3 ]
Wang, Dan [1 ,2 ]
Chen, Yongsheng [4 ]
Jiang, Lei [3 ]
机构
[1] Beijing Univ Aeronaut & Astronaut, Beijing 100191, Peoples R China
[2] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, BNLMS, Beijing 100191, Peoples R China
[4] Nankai Univ, Coll Chem, Inst Polymer Chem, Tianjin 300071, Peoples R China
关键词
two-dimensional; graphene; photoanode; dye-sensitized solar cells; charge transport; TIO2 NANOTUBE ARRAYS; CONVERSION EFFICIENCY; CARBON; REDUCTION; GRAPHITE; ELECTRODES; SCAFFOLDS; IMPEDANCE; FILMS;
D O I
10.1021/nn901660v
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
As a novel two-dimensional (2D) material, graphene shows great benefits in electric and material science. Compared to 1D nanomaterials, it may show more excellent properties. Here, we introduced graphene as 2D bridges into the nanocrystalline electrodes of dye-sensitized solar cells, which brought a faster electron transport and a lower recombination, together with a higher light scattering. On the basis of these advantages, the short-circuit current density was increased by 45% without sacrificing the open-circuit voltage, and the total conversion efficiency was 6.97%, which was increased by 39%, comparing with the nanocrystalline titanium dioxide photoanode, and it was also much better than the 1D nanomaterial composite electrode.
引用
收藏
页码:887 / 894
页数:8
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