Anomalous Jahn-Teller distortions in La0.75Ca0.25MnO3 system: An X-ray absorption study

被引:2
作者
Brunelli, M [1 ]
Lanzara, A [1 ]
Saini, NL [1 ]
Bianconi, A [1 ]
Valletta, A [1 ]
Radaelli, PG [1 ]
机构
[1] INST MAX VON LAUE PAUL LANGEVIN,F-38043 GRENOBLE,FRANCE
来源
JOURNAL OF SUPERCONDUCTIVITY | 1997年 / 10卷 / 04期
关键词
Jahn-Teller effect; La0.75Ca0.25MnO3; giant magnetoresistance;
D O I
10.1007/BF02765710
中图分类号
O59 [应用物理学];
学科分类号
摘要
Mn K-edge X-ray absorption near edge structure (XANES) measurements have been made to study the temperature-dependent lattice effects in the La0.75Ca0.25MnO3 system. The high-resolution XANES spectra recorded with high signal-to-noise ratio have allowed us to study the temperature dependence of the Jahn-Teller splitting indicated directly by the dipole forbidden pre-peaks corresponding to transition in Mn 3d states. The results show splitting of the e(g) state in its two orbitals (d(x2-y2) and d(3z2-r2)). The energy splitting shows anomalous temperature dependence across the giant magnetoresistance transition temperature.
引用
收藏
页码:315 / 318
页数:4
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