Self-Assembly from Two-Dimensional Layered Networks to Tetranuclear Structures: Syntheses, Structures, and Properties of Four Copper-Thiacalix[4]arene Compounds

被引：22

作者：

Bi, Yanfeng ^{[1
,2
]}

Liao, Wuping ^{[1
]}

Wang, Xinwu ^{[1
]}

Deng, Ruiping ^{[1
]}

Zhang, Hongjie ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 33期

基金：

中国国家自然科学基金;

关键词：

Calixarenes; Copper; Cluster chemistry; Solvothermal synthesis; Self-assembly; CLUSTER COMPLEXES; TRANSITION-METAL; CHEMISTRY;

D O I：

10.1002/ejic.200900699

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new copper-thiacalix[4]arene compounds, [Cu-2(1)-Cl-2(H(4)TC4A)](CH3OH) (1) and [Cu(I)2Cl(2)(H(4)PTC4A)](CH3OH)(CHCl3)(0.5) (2) (where H(4)TC4A = p-tert-butylthiacalix[4]arene and H(4)PTC4A = p-phenylthiacalix[4]arene), were synthesized by the solvothermal method in the mixed CH3OH/CHCl3 (1: 1) solvent and reassembled in air at room temperature to two other structures, [(Cu4Cl3)-Cl-II(HCO2)(TC4A)(CH3-OH)(2)(H2O)](CHCl3)(CH3OH)(2.7) (3) and [(Cu4Cl4)-Cl-II(PTC4A)(CH3OH)(4)] (4), respectively. All these four compounds were characterized by TG analyses, FTIR spectroscopy, and singlecrystal X-ray diffraction analyses. Compounds 1 and 2 feature two-dimensional layered networks, while compounds 3 and 4 are assembled by some tetranuclear units. The luminescence of compounds 1 and 2 in the solid state and magnetic properties of compound 3 were studied. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：4989 / 4994

页数：6

共 30 条

[1] Koilands from thiophiles: mercury(II) clusters from thiacalixarenes [J].