Monomolecular endothermic reaction of n-decane catalyzed by HZSM-5 films

被引：6
|
作者：
Zhang, Xiangwen [1 ]
Xing, Enhui [1 ]
Chen, Gexin [1 ]
Mi, Zhentao [1 ]
机构：
[1] Tianjin Univ, Sch Chem Engn, Tianjin 300072, Peoples R China
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2006年 / 89卷 / 02期
基金：
国家高技术研究发展计划(863计划);
关键词：
endothermic fuels; catalytic cracking; zeolite films; membrane catalysts; cokes; n-decane;
D O I：
10.1007/s11144-006-0133-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This paper reports the possibility of in situ synthesis of HZSM-5 zeolite films on tubular steel substrate for the improved potential chemical heat sink of fuels, and the performance of prepared membrane catalysts in the endothermic catalytic cracking of n-decane. Through hydrothermal crystallization, a zeolite/steel composite was obtained which consists of a continuous zeolite film that strongly attaches to the substrate surface. The membrane catalysts are active enough for the n-decane catalytic cracking to provide endothermal ability, and also can suppress the formation of carbon deposits compared with thermal cracking.
引用
收藏
页码：237 / 245
页数：9
相关论文
共 50 条
  • [1] Monomolecular endothermic reaction of n-decane catalyzed by HZSM-5 films
    Xiangwen Zhang
    Enhui Xing
    Gexin Chen
    Zhentao Mi
    Reaction Kinetics and Catalysis Letters, 2006, 89 : 237 - 245
  • [2] Effect of phosphorus and mesopore modification on the HZSM-5 zeolites for n-decane cracking
    Sang, Yu
    Li, Hansheng
    JOURNAL OF SOLID STATE CHEMISTRY, 2019, 271 : 326 - 333
  • [3] MONOMOLECULAR AND BIOMOLECULAR MECHANISMS OF PARAFFIN CRACKING - N-BUTANE CRACKING CATALYZED BY HZSM-5
    KRANNILA, H
    HAAG, WO
    GATES, BC
    JOURNAL OF CATALYSIS, 1992, 135 (01) : 115 - 124
  • [4] Hydroconversion of n-decane on Pt/HZSM-5 bifunctional catalysts: effect of the Si/Al ratio of the zeolite on selectivities
    Ahcène Soualah
    Jean-Louis Lemberton
    Ludovic Pinard
    Mohamed Chater
    Patrick Magnoux
    Kjell Moljord
    Reaction Kinetics, Mechanisms and Catalysis, 2010, 101 : 209 - 219
  • [5] Synthesis and performance of pillared HZSM-5 nanosheet zeolites for n-decane catalytic cracking to produce light olefins
    Tian, Yajie
    Zhang, Bofeng
    Liang, Hairui
    Hou, Xu
    Wang, Li
    Zhang, Xiangwen
    Liu, Guozhu
    APPLIED CATALYSIS A-GENERAL, 2019, 572 : 24 - 33
  • [6] Coking and gas products behavior of supercritical n-decane over NiO nanoparticle/nanosheets modified HZSM-5
    Long, Lin
    Zhou, Weixing
    Qiu, Yunfeng
    Lan, Zhenzhong
    ENERGY, 2020, 192
  • [7] Synergetic Regulation of the Microstructure and Acidity of HZSM-5/MCM-41 for Efficient Catalytic Cracking of n-Decane
    Zhang, Yaoyuan
    Wu, Qin
    Zhang, Kun
    Shi, Daxin
    Jia, Shujun
    Chen, Kangcheng
    Li, Hansheng
    LANGMUIR, 2023, 9 (3494-3501) : 3494 - 3501
  • [8] Hydroconversion of n-decane on Pt/HZSM-5 bifunctional catalysts: effect of the Si/Al ratio of the zeolite on selectivities
    Soualah, Ahcene
    Lemberton, Jean-Louis
    Pinard, Ludovic
    Chater, Mohamed
    Magnoux, Patrick
    Moljord, Kjell
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2010, 101 (01) : 209 - 219
  • [9] Controllably tailoring external surface sites of nanosheet HZSM-5 for maximizing light olefins in catalytic cracking of n-decane
    Tiantian Zhu
    Hairui Liang
    Bofeng Zhang
    Yajie Tian
    Guozhu Liu
    Chinese Journal of Chemical Engineering, 2021, 38 (10) : 276 - 285
  • [10] Hydroconversion of n-decane on bifunctional Ni/HZSM-5 catalysts: effect of zeolite Si/Al ratio and metal loading
    Romero, MD
    Calles, JA
    Rodriguez, A
    de Lucas, A
    ANALES DE QUIMICA-INTERNATIONAL EDITION, 1998, 94 (02): : 71 - 77
12345