{Tris[(dimethylamino)dimethylsilyl]methyl}magnesium iodide. A Grignard reagent without a carbon-magnesium bond?

被引：18

作者：

Eaborn, C

Farook, A

Hitchcock, PB

Smith, JD

机构：

[1] School of Chemistry, Physics and Environmental Science, University of Sussex

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 04期

关键词：

D O I：

10.1021/om960891c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of (Me(2)NMe(2)Si)(3)CI with Mg gives the Grignard reagent (Me(2)NMe(2)Si)(3)CMgI, in which all three N atoms are coordinated to Mg and there is a planar carbanionic center, suggesting the absence of C ... Mg bonding.

引用

页码：503 / 504

页数：2

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