Bioprivileged molecules: creating value from biomass

被引:143
作者
Shanks, Brent H. [1 ,2 ]
Keeling, Peter L. [1 ]
机构
[1] Iowa State Univ, Ctr Biorenewable Chem CBiRC, Ames, IA 50011 USA
[2] Iowa State Univ, Dept Chem & Biol Engn, Ames, IA 50011 USA
基金
美国国家科学基金会;
关键词
TRIACETIC ACID LACTONE; DIVERSITY-ORIENTED SYNTHESIS; BUILDING-BLOCK CHEMICALS; SACCHAROMYCES-CEREVISIAE; MUCONIC ACID; PRIVILEGED STRUCTURES; BIOLOGICAL CATALYSIS; COMPUTATIONAL TOOLS; METABOLIC NETWORKS; SYNTHETIC BIOLOGY;
D O I
10.1039/c7gc00296c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The petrochemical industry is built on C2-C4 alkenes and aromatics as intermediate molecules, which are converted to a range of products. This industry is highly developed with little opportunity for new chemical products. In comparison biological-derived intermediates from biomass have the potential to introduce a new set of intermediate molecules, which can be converted to molecules that directly replace petrochemicals. Even more promising is the potential to convert biological-derived intermediates to novel chemical species that impart enhanced performance properties in their end use. Here the concept of bioprivileged molecules is introduced as a useful new paradigm for developing biobased chemicals. Included are muconic acid, 5-hydroxymethylfurfural and triacetic acid lactone as example bioprivileged molecules. Also, discussed is the research needed to move this concept forward.
引用
收藏
页码:3177 / 3185
页数:9
相关论文
共 65 条
[1]   Opportunities and challenges in biological lignin valorization [J].
Beckham, Gregg T. ;
Johnson, Christopher W. ;
Karp, Eric M. ;
Salvachua, Davinia ;
Vardon, Derek R. .
CURRENT OPINION IN BIOTECHNOLOGY, 2016, 42 :40-53
[2]   Catalytic routes towards acrylic acid, adipic acid and ε-caprolactam starting from biorenewables [J].
Beerthuis, Rolf ;
Rothenberg, Gadi ;
Shiju, N. Raveendran .
GREEN CHEMISTRY, 2015, 17 (03) :1341-1361
[3]  
Bernaerts K., 2016, Applied Biocatalysis: From Fundamental Science to Industrial Applications, P405, DOI 10.1002/9783527677122.ch17
[4]   Dehydration of D-fructose to hydroxymethylfurfural in sub- and supercritical fluids [J].
Bicker, M ;
Kaiser, D ;
Ott, L ;
Vogel, H .
JOURNAL OF SUPERCRITICAL FLUIDS, 2005, 36 (02) :118-126
[5]   Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].
Bozell, Joseph J. ;
Petersen, Gene R. .
GREEN CHEMISTRY, 2010, 12 (04) :539-554
[6]  
Brase S., 2016, PRIVILEGED SCAFFOLDS, P478
[7]   A planning strategy for diversity-oriented synthesis [J].
Burke, MD ;
Schreiber, SL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (01) :46-58
[8]   Bioinformatics for the synthetic biology of natural products: integrating across the Design-Build-Test cycle [J].
Carbonell, Pablo ;
Currin, Andrew ;
Jervis, Adrian J. ;
Rattray, Nicholas J. W. ;
Swainston, Neil ;
Yan, Cunyu ;
Takano, Eriko ;
Breitling, Rainer .
NATURAL PRODUCT REPORTS, 2016, 33 (08) :925-932
[9]   Metabolic engineering of Saccharomyces cerevisiae for the production of triacetic acid lactone [J].
Cardenas, Javier ;
Da Silva, Nancy A. .
METABOLIC ENGINEERING, 2014, 25 :194-203
[10]   Triacetic acid lactone as a potential biorenewable platform chemical [J].
Chia, Mei ;
Schwartz, Thomas J. ;
Shanks, Brent H. ;
Dumesic, James A. .
GREEN CHEMISTRY, 2012, 14 (07) :1850-1853