Reactivity of [ReOX3(AsPh3)2] (X = Cl, Br) complexes towards gaseous nitric oxide.: Crystal, molecular and electronic structure of [ReBr3(NO)(OAsPh3)2], [ReCl3(NO)(AsPh3)2][ReCl4(AsPh3)2], [ReCl4(OAsPh3)2] and [ReBr3(NO)(AsPh3)2]

被引：16

作者：

Machura, B

Dziegielewski, JO

Michalik, S

Bartczak, TJ

Kruszynski, R

Kusz, J

机构：

[1] Silesian Univ, Inst Chem, Dept Inorgan & Radiat Chem, PL-40006 Katowice, Poland

[2] Tech Univ Lodz, Inst Gen & Ecol Chem, Xray Crystallog Lab, PL-90924 Lodz, Poland

[3] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland

来源：

POLYHEDRON | 2002年 / 21卷 / 25-26期

关键词：

rhenium; nitrosyl; X-ray structures; electronic structures; nitric oxide;

D O I：

10.1016/S0277-5387(02)01254-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the complexes [ReOX3(AsPh3)(2)] (X = Cl, Br) with gaseous nitric oxide and the reactions of the compounds [NBu4](2)[ReX5(NO)] (X = Cl, Br) with an excess of triphenylarsine have been examined. [ReOBr3(AsPh3)(2)] reacts with nitric oxide to give mer,cis-[ReBr3(NO)(OAsPh3)(2)] (1), whereas the reaction of the chlorine oxocomplex with NO leads to three products: [ReCl3(NO)(OAsPh3)(2)] (2), mer, trans -[ReCl3(NO)(AsPh3)(2)][ReCl4(AsPh3)(2)] (3) and cis-[ReCl4(OAsPh3)(2)] (4). The compounds [NBu4](2)[ReX5(NO)] (X = Cl, Br) react with an excess of AsPh3 to give 3 and mer, trans-[ReBr3(NO)(AsPh3)(2)] (5), respectively. The complexes obtained in these reactions have been characterised by IR, UV-Vis and magnetical measurements. Crystal and molecular structures have been determined for complexes 1 and 3-5. EPR spectra have been recorded for compounds 1 and 5. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：2617 / 2629

页数：13

共 45 条

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INORGANICA CHIMICA ACTA, 2013, 405 : 455 - 460
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[35] Metal complexes as host molecules: The X-ray crystal structure of [Mo{HB(3,5-Me(2)pz)(3)}(NO){1,3-O-2-4-CH2(C6H13)C6H2}](4)center dot 2CH(2)Cl(2)
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[36] Synthesis and spectroscopic properties of Mo(VI) complexes with phosphine oxide ligands and the crystal structures of [MoO2X2(OPMe3)2] (X=Cl or Br) and [MoO2Br2{0-C6H4(P(O)Ph2)2}• 2CH2Cl2
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[37] Synthesis, spectroscopic investigation, structural characterization and DFT calculation of the complexes [ReX2(N2COPh)(4-PhPyr)(PPh3)2] (X = Cl, Br)
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[38] Syntheses and characterization of some chloro, methoxy, and mercapto derivatives of [Ru(η2-2,2′-bipyridine)3]2+ 2PF6:: crystal and molecular structures of [Ru(η2-2,2′-bipyridine)2(η2-4,4′-(X)2-2,2′-bipyridine)]2+2PF6- (X = Cl, OCH3)
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[39] Ruthenium complexes as nitric oxide donors and scavengers. Synthesis and crystal and molecular structure for mer,trans-[RuIICl3(NO+)(N-4-ethylisonicotinate)2], and mer,trans-[RuIIICl3(N-CH3CN)(N-4-ethylisonicotinate)2] as obtained via UV-photochemical activation of {RuII(NO+)}3+-core parent complex in acetonitrile solution
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