Reactivity of [ReOX3(AsPh3)2] (X = Cl, Br) complexes towards gaseous nitric oxide.: Crystal, molecular and electronic structure of [ReBr3(NO)(OAsPh3)2], [ReCl3(NO)(AsPh3)2][ReCl4(AsPh3)2], [ReCl4(OAsPh3)2] and [ReBr3(NO)(AsPh3)2]

被引：16
|
作者：
Machura, B
Dziegielewski, JO
Michalik, S
Bartczak, TJ
Kruszynski, R
Kusz, J
机构：
[1] Silesian Univ, Inst Chem, Dept Inorgan & Radiat Chem, PL-40006 Katowice, Poland
[2] Tech Univ Lodz, Inst Gen & Ecol Chem, Xray Crystallog Lab, PL-90924 Lodz, Poland
[3] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland
来源：
POLYHEDRON | 2002年 / 21卷 / 25-26期
关键词：
rhenium; nitrosyl; X-ray structures; electronic structures; nitric oxide;
D O I：
10.1016/S0277-5387(02)01254-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of the complexes [ReOX3(AsPh3)(2)] (X = Cl, Br) with gaseous nitric oxide and the reactions of the compounds [NBu4](2)[ReX5(NO)] (X = Cl, Br) with an excess of triphenylarsine have been examined. [ReOBr3(AsPh3)(2)] reacts with nitric oxide to give mer,cis-[ReBr3(NO)(OAsPh3)(2)] (1), whereas the reaction of the chlorine oxocomplex with NO leads to three products: [ReCl3(NO)(OAsPh3)(2)] (2), mer, trans -[ReCl3(NO)(AsPh3)(2)][ReCl4(AsPh3)(2)] (3) and cis-[ReCl4(OAsPh3)(2)] (4). The compounds [NBu4](2)[ReX5(NO)] (X = Cl, Br) react with an excess of AsPh3 to give 3 and mer, trans-[ReBr3(NO)(AsPh3)(2)] (5), respectively. The complexes obtained in these reactions have been characterised by IR, UV-Vis and magnetical measurements. Crystal and molecular structures have been determined for complexes 1 and 3-5. EPR spectra have been recorded for compounds 1 and 5. (C) 2002 Elsevier Science Ltd. All rights reserved.
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收藏
页码：2617 / 2629
页数：13
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