Synthesis of aziridines by visible-light induced decarboxylative cyclization of N-aryl glycines and diazo compounds

被引:19
|
作者
Liu, Yong [1 ,2 ,3 ]
Dong, Xichang [1 ]
Deng, Guojun [2 ,3 ]
Zhou, Lei [1 ]
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China
[2] Minist Educ, Key Lab Environm Friendly Chem & Applicat, Xiangtan 411105, Peoples R China
[3] Xiangtan Univ, Coll Chem, Xiangtan 411105, Peoples R China
基金
中国国家自然科学基金;
关键词
visible light; diazo compound; decarboxylation; aza-Darzens reaction; PHOTOREDOX CATALYSIS; REACTIVITY; FUNCTIONALIZATION; GENERATION; CONVERSION; IMINES; AMINES; ACIDS;
D O I
10.1007/s11426-015-5513-8
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A visible-light induced decarboxylative aza-Darzens reaction between N-aryl glycines and diazo compounds was developed, which affords various mono-substituted aziridines in good yields.
引用
收藏
页码:199 / 202
页数:4
相关论文
共 50 条
  • [31] Visible-Light Photoredox-Catalyzed Decarboxylative Double Difluoromethylation of β,γ-Unsaturated Carboxylic Acids for the Synthesis of Difluoromethylated Allylic Compounds
    Yao, Zhen
    Li, Gang
    Zhou, Ying
    Xu, Lijin
    Xue, Dong
    ADVANCED SYNTHESIS & CATALYSIS, 2023, 365 (02) : 224 - 229
  • [32] Synthesis of N-Containing Heterocyclic Compounds Using Visible-light Photoredox Catalysis
    Zhou, Lei
    Hossain, Mohammad Lokman
    Xiao, Tiebo
    CHEMICAL RECORD, 2016, 16 (01): : 319 - 334
  • [33] Visible-light-promoted tandem decarboxylation coupling/cyclization of N-aryl glycines with quinoxalinones: Easy access to tetrahydroimidazo [1,5-a]quinoxalin-4(5H)-ones
    Tang, Zhen
    Pi, Chao
    Wu, Yangjie
    Cui, Xiuling
    GREEN SYNTHESIS AND CATALYSIS, 2024, 5 (01): : 31 - 34
  • [34] Photoredox-Catalyzed Synthesis of N-Aryl γ-Lactams via Radical Addition-Cyclization Cascade
    Azim, Aznur
    Vasudevan, Vidhul
    Mandal, Tanumoy
    De Sarkar, Suman
    SYNTHESIS-STUTTGART, 2025, 57 (02): : 472 - 480
  • [35] Photocatalyst- and transition-metal-free α-allylation of N-aryl tetrahydroisoquinolines mediated by visible light
    Li, Zhuohua
    Ma, Pengju
    Tan, Yongzhu
    Liu, Yufei
    Gao, Min
    Zhang, Yujun
    Yang, Bo
    Huang, Xuan
    Gao, Yuan
    Zhang, Junmin
    GREEN CHEMISTRY, 2020, 22 (03) : 646 - 650
  • [36] Metal-free synthesis of ketones by visible-light induced aerobic oxidative radical addition of aryl hydrazines to alkenes
    Ding, Ya
    Zhang, Wenkai
    Li, Hao
    Meng, Yunge
    Zhang, Te
    Chen, Qiu-Yun
    Zhu, Chunyin
    GREEN CHEMISTRY, 2017, 19 (13) : 2941 - 2944
  • [37] Visible-Light-Induced Regioselective Alkylation of Coumarins via Decarboxylative Coupling with N-Hydroxyphthalimide Esters
    Jin, Can
    Yan, Zhiyang
    Sun, Bin
    Yang, Jin
    ORGANIC LETTERS, 2019, 21 (07) : 2064 - 2068
  • [38] Visible Light-Induced Decarboxylative Peroxidation of Carboxylic Acids: Metal-Free Synthesis of Benzyl Peroxides
    Lou, Chenhao
    Feng, Yuting
    Huang, Qiuwei
    Lv, Leiyang
    Li, Zhiping
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 12 (11)
  • [39] Synthesis of Quinolines by Visible-Light Induced Radical Reaction of Vinyl Azides and -Carbonyl Benzyl Bromides
    Wang, Qile
    Huang, Jun
    Zhou, Lei
    ADVANCED SYNTHESIS & CATALYSIS, 2015, 357 (11) : 2479 - 2484
  • [40] Visible Light-Driven α-Alkylation of N-Aryl tetrahydroisoquinolines Initiated by Electron Donor-Acceptor Complexes
    Xia, Qing
    Li, Yufei
    Wang, Xinmin
    Dai, Peng
    Deng, Hongping
    Zhang, Wei-Hua
    ORGANIC LETTERS, 2020, 22 (18) : 7290 - 7294