Solvent-induced two-photon absorption of a push-pull molecule

被引：1
作者：
Luo, Y
Norman, P
Macak, P
Ågren, H
机构：
[1] Royal Inst Technol, Div Theoret Chem, S-10044 Stockholm, Sweden
[2] Univ Stockholm, FYSIKUM, S-11385 Stockholm, Sweden
[3] Linkoping Univ, Dept Phys & Measurement Technol, S-58183 Linkoping, Sweden
来源：
JOURNAL OF PHYSICAL CHEMISTRY A | 2000年 / 104卷 / 20期
关键词：
D O I：
10.1021/jp993803l
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Solvent-induced two-photon absorption cross sections are calculated for a push-pull molecule in solutions using both self-consistent reaction field and internal finite field approaches. It is shown analytically and numerically that the results from the two methods can be connected through induced local reaction field factors. The two-photon cross sections of the studied push-pull polyene are found to be rather insensitive to the choice of cavity shape. The solvent dependence of the two-photon absorption displays a pattern different from that of the first hyperpolarizability.
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页码：4718 / 4722
页数：5
相关论文
共 36 条
  • [1] Rational design of molecules with large hyperpolarizabilities. Electric field, solvent polarity, and bond length alternation effects on merocyanine dye linear and nonlinear optical properties
    Albert, IDL
    Marks, TJ
    Ratner, MA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (23) : 9714 - 9725
  • [2] Design of organic molecules with large two-photon absorption cross sections
    Albota, M
    Beljonne, D
    Brédas, JL
    Ehrlich, JE
    Fu, JY
    Heikal, AA
    Hess, SE
    Kogej, T
    Levin, MD
    Marder, SR
    McCord-Maughon, D
    Perry, JW
    Röckel, H
    Rumi, M
    Subramaniam, C
    Webb, WW
    Wu, XL
    Xu, C
    [J]. SCIENCE, 1998, 281 (5383) : 1653 - 1656
  • [3] Bottcher C.J. F., 1973, THEORY ELECT POLARIZ, V1
  • [4] Two-photon-induced fluorescence
    Callis, PR
    [J]. ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1997, 48 (01) : 271 - 297
  • [5] Solvent effects on linear and nonlinear optical properties of donor-acceptor polyenes: Investigation of electronic and vibrational components in terms of structure and charge distribution changes
    Cammi, R
    Mennucci, B
    Tomasi, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (34) : 8834 - 8847
  • [6] Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication
    Cumpston, BH
    Ananthavel, SP
    Barlow, S
    Dyer, DL
    Ehrlich, JE
    Erskine, LL
    Heikal, AA
    Kuebler, SM
    Lee, IYS
    McCord-Maughon, D
    Qin, JQ
    Röckel, H
    Rumi, M
    Wu, XL
    Marder, SR
    Perry, JW
    [J]. NATURE, 1999, 398 (6722) : 51 - 54
  • [7] 2-PHOTON LASER SCANNING FLUORESCENCE MICROSCOPY
    DENK, W
    STRICKLER, JH
    WEBB, WW
    [J]. SCIENCE, 1990, 248 (4951) : 73 - 76
  • [8] GAUSSIAN-BASIS SETS FOR USE IN CORRELATED MOLECULAR CALCULATIONS .1. THE ATOMS BORON THROUGH NEON AND HYDROGEN
    DUNNING, TH
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (02) : 1007 - 1023
  • [9] FLYTZANIS C, 1975, QUANTUM ELECTRON, V1, P88
  • [10] Frisch M. J., 2016, Gaussian, V16
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