ZnO:CeO2-based nanopowders with low catalytic activity as UV absorbers

被引:92
作者
de Lima, Juliana Fonseca [1 ]
Martins, Renata Figueredo [1 ]
Neri, Claudio Roberto [1 ]
Serra, Osvaldo Antonio [1 ]
机构
[1] USP, FFCLRP, Dept Chem, BR-14040901 Ribeirao Preto, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
Cerium oxide; Ceria; Zinc oxide; Rare earth; Sunscreen; UV protection; OXIDE-DOPED CERIA; CEO2 FINE POWDER; SHIELDING PROPERTIES; PARTICLES;
D O I
10.1016/j.apsusc.2009.06.071
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ultrafine systems of zinc oxide and cerium oxide for use as ultraviolet filter were synthesized by a non-alkoxide sol-gel process at different temperatures, to obtain solid materials (40 and 70 degrees C), that were characterized by X-ray diffraction, scanning electronmicroscopy, UV-vis reflectance. Their catalytic and photocatalytic activities were also evaluated. ZnO:CeO2 systems present higher UV absorption and transparency in the visible region. The photocatalytic activity of ZnO:CeO2 systems for the oxidation of organic materials is much smaller than that of titania, ceria and zinc oxide, suggesting that ZnO:CeO2 systems are promising candidates for use as optical materials in UV-filters. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:9006 / 9009
页数:4
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