Substituent effects in the rhodium-catalyzed hydroformylation of olefins using bis(diarylphosphino)methylamino ligands

被引：32

作者：

Reetz, MT

Waldvogel, SR

Goddard, R

机构：

[1] Max-Planck-Inst. fur Kohlenforschung, D-45470 Mülheim/Ruhr

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 34期

关键词：

D O I：

10.1016/S0040-4039(97)01345-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rhodium-complexes of bis(diarylphosphino)methylamino ligands RN(CH2PPh2)(2) are active catalysts in the hydroformylation of 1-octene and 2-vinylnaphthalene, regioselectivity (n/iso-ratio) and catalyst activity (TOF) depending upon the nature of the para-substituent in the N-aryl moiety (R = C6H5, p-CF3-C6H4, p-NMe2-C6H4). (C) 1997 Elsevier Science Ltd.

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页码：5967 / 5970

页数：4

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